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Development of Self-Assembled Monolayers of Single-Walled Carbon Nanotubes Assisted Cysteamine on Gold Electrodes

机译:金电极上单壁碳纳米管辅助半胱胺自组装单分子膜的开发

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摘要

A highly organized self-aligned perpendicular self-assembled monolayers (SAM) by Single-walled carbon nano-tube (SWCNT) assisted Cysteamine (2-Aminoethanethiol, AET) were fabricated on gold single crystal substrates. The fabricated nano-surfaces were investigated specially using FT-IR, cyclic voltammetry (CV), Raman spectroscopy, electrochemical quartz crystal microbalance (EQCM), and atomic force microscopy (AFM) techniques. The SWCNTs were cut into short pipes by chemical oxidation and then thiol-derivatized at the open ends. The perpendicular aggregation of SWCNT-AET on chemically polished Au(111) substrates was fabricated by their spontaneous chemical bonding between carboxyl derivatized SWCNT-COOH and AET SAM on Au(111), via peptide bonds, or directly by synthesized SWCNT-AET composites. Raman spectroscopy and AFM surface images clearly revealed that the SWCNT-AET (dia. 15-42 nm) has been perpendicular organized on gold substrates, forming a SAM with a perpendicular orientation.
机译:在金单晶衬底上制备了由单壁碳纳米管(SWCNT)辅助的半胱胺(2-氨基乙硫醇,AET)组成的高度组织化的自对准垂直自组装单分子膜(SAM)。使用FT-IR,循环伏安法(CV),拉曼光谱法,电化学石英晶体微天平(EQCM)和原子力显微镜(AFM)技术对制备的纳米表面进行了专门研究。通过化学氧化将SWCNT切成短管,然后在开口端进行硫醇衍生化。 SWCNT-AET在化学抛光的Au(111)基材上的垂直聚集是通过羧基衍生的SWCNT-COOH与AET SAM在Au(111)上的自发化学键结合,通过肽键或直接由合​​成的SWCNT-AET复合材料制备的。拉曼光谱和AFM表面图像清楚地表明,SWCNT-AET(直径15-42 nm)已经垂直组织在金基底上,形成具有垂直方向的SAM。

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