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首页> 外文期刊>International Journal of Global Warming >Effect of supercritical CO2 on various rank coals: implications for CO2 sequestration in coal seams with enhanced coalbed methane recovery
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Effect of supercritical CO2 on various rank coals: implications for CO2 sequestration in coal seams with enhanced coalbed methane recovery

机译:超临界CO2对各种等级煤的影响:增强煤层储存煤层中CO2螯合的影响

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摘要

Sequestration of CO2 in coal seams with enhanced coalbed methane recovery (CO2-ECBM) can mitigate CO2 emissions. In this work, the effects of the supercritical CO2 fluid on the physicochemical property of coals were elucidated. The results show that CO2 interaction can mobilise the volatile hydrocarbons in the coal matrix and subsequently result in the decrease of volatile matter content. The volatile matter contents of coals decrease with temperature, pressure and injection rate of CO2 interaction. The extracted volatile matters are of biological toxicity, thus CO2-ECBM process should be operated at the optimum temperature, pressure and CO2 injection rate. The moisture contents of Zhangji coal and Liulin coal after CO2 interaction increase which implies that the pore morphology of the above two coals grows up. For low rank Bulianta coal and high rank Qinshui coal, the swelling effect induced by CO2 is dominant. Thus, the moisture content after CO2 interaction decreases in comparison with the raw state.
机译:煤层煤层复苏(CO2-ECBM)的煤层中二氧化碳的封存可以减轻二氧化碳排放。在这项工作中,阐明了超临界CO2流体对煤的物理化学性质的影响。结果表明,CO2相互作用可以动员煤基质中的挥发性烃,随后导致挥发性物质含量的降低。煤的挥发性物质含量随着CO 2相互作用的温度,压力和注射速率而降低。提取的挥发性物质具有生物毒性,因此CO 2-ECBM工艺应在最佳温度,压力和CO 2注射速率下操作。二氧化碳相互作用增加后张吉煤和血管素煤的水分含量意味着上述两煤的孔形态增长。对于低等级的Bulianta煤和高级秦水煤,CO2诱导的肿胀效应是显性的。因此,与原始状态相比,CO2相互作用后的水分含量降低。

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