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Characterization of Nanoclays and Incorporation in Copolymer of Styrene-Ethylene-Propylene-Styrene (SEPS)

机译:纳米阵列的表征及苯乙烯 - 乙烯 - 丙烯 - 苯乙烯共聚物(SEP)的共聚物

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摘要

The objective of this work is to evaluate the effect nanoclays inclusion on copolymer of Styrene-Ethylene-Propylene-Styrene (SEPS) at two compositions of nanoclay (0 and 3%, w/w). The resulting nanoclay was characterized by XPvD, SEM, EDX. Membranes modified with nanoclay were studied by water uptake, porosity and DSC analysis. The XRD patterns indicated that both samples of nanoclays, obtenied of cosmetic and molding clay, were suitable for the modification because of the increasing of the polymer-nanoclay surface area after this procedure. SEM analysis revealed an agglomeration phenomenon after contacting the surfactant-modified nanoclays with air. The incorporation of surfactant hydrocarbon chains in the MMT structure was confirmed by the EDX results. Finally, DSC analysis showed good stability of modified membranes at temperature changes, suggesting that this material could be used in applications that require temperatures range less than 150 °C.
机译:本作作品的目的是在纳米粘土(0和3%,W / W)的两种组合物中,评价纳米粘土纳入苯乙烯 - 乙烯 - 丙烯 - 苯乙烯(SEPS)的共聚物。 得到的纳米粘土的特征在于XPVD,SEM,EDX。 通过水吸收,孔隙率和DSC分析研究了用纳米粘土改性的膜。 XRD图案表明,由于在该过程之后的聚合物 - 纳米粘土表面积的增加,纳米粘土的样品,嵌入化妆品和模塑粘土均适用于改性。 SEM分析显示了在用空气接触表面活性剂改性的纳米粘土后的凝聚现象。 通过EDX结果证实了MMT结构中的表面活性剂烃链的掺入。 最后,DSC分析显示在温度变化下改性膜的良好稳定性,表明该材料可用于需要温度范围小于150°C的应用。

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