Application of a Polypyrrole/Carboxy Methyl Cellulose Ion Imprinted Polymer in the Electrochemical Detection of Mercury in Water

Velempini Tarisai; Pillay Kriveshini; Mbianda Xavier Y.; Arotiba Omotayo A.

摘要

Abstract > Sulphur containing carboxy methyl ion imprinted polymers (S‐IIPs) were applied as an electrode modifier for the electrochemical detection of Hg(II). A bare glassy carbon electrode (GCE) was modified by electro‐polymerizing a layer of pyrrole and then drop coating with S‐IIPs. The bare GCE, GCE/polypyrrole (GCE/PPy), GCE/polyprrole/non‐ion imprinted polymers (GCE/PPy/NIPs) and the GCE/polypyrrole/sulphur ion imprinted polymers (GCE/PPy/S‐IIPs) electrodes were characterised with Fourier Transmission Infrared (FTIR) and electrochemical impendence spectroscopy (EIS). The square wave anodic stripping voltammetry (SWASV) optimised conditions for the GCE/PPy/S‐IIPs were: a pH of 3, deposition potential of ?1.0?V, pre‐concentration time of 60?s and 0.1?M HCl supporting electrolyte. The developed ion imprinted polymer electrochemical sensor was applied in the detection of Hg(II) in water. A detection limit of 0.1?μg?L ?1 was calculated within a concentration range of 20–800?μg?L ?1 . The sensor was selective in the presence of interfering ions and method was validated with inductively coupled plasma‐optical emission spectrometry (ICP‐OES) using real water and standard water samples. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“En”> <标题类型=“main”>含有羧基甲基离子压印聚合物（S-IIPS）的含硫作为电极改性剂HG（II）的电化学检测。通过电聚合吡咯并用S-IIPS涂布涂层来改变裸玻璃碳电极（GCE）。裸GCE，GCE /聚吡咯（GCE / PPY），GCE / POVERPROLE /非离子印迹聚合物（GCE / PPY / NIPS）和GCE /滤吡咯/硫离子压印聚合物（GCE / PPY / S-IIPS）电极是具有傅立叶传输红外（FTIR）和电化学常识光谱（EIS）的特征。用于GCE / PPY / S-IIPS的方波阳极剥离伏安法（SWASV）优化条件是：pH为3，沉积电位？1.0·v，预浓度为60？s和0.1μl的HCl负载电解质。研制的离子压印的聚合物电化学传感器用于在水中检测Hg（II）。检测限为0.1≤μg≤1Ω1Ω1/ sup>在20-800Ωμg·l 1 </ sup>的浓度范围内计算。在干扰离子存在下，传感器选择性，使用真正的水和标准水样品用电感耦合等离子体光发射光谱法（ICP-OES）验证。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第11期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Velempini Tarisai&option=202" target="_blank" rel="nofollow">Velempini Tarisai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pillay Kriveshini&option=202" target="_blank" rel="nofollow">Pillay Kriveshini;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mbianda Xavier Y.&option=202" target="_blank" rel="nofollow">Mbianda Xavier Y.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Arotiba Omotayo A.&option=202" target="_blank" rel="nofollow">Arotiba Omotayo A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Applied ChemistryUniversity of JohannesburgSouth Africa;</p> <p>Department of Applied ChemistryUniversity of JohannesburgSouth Africa;</p> <p>Department of Applied ChemistryUniversity of JohannesburgSouth Africa;</p> <p>Department of Applied ChemistryUniversity of JohannesburgSouth Africa;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mercury&option=203" rel="nofollow">Mercury;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ion-imprinted polymer&option=203" rel="nofollow">Ion-imprinted polymer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polypyrrole&option=203" rel="nofollow">polypyrrole;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=square-wave anodic stripping voltammetry&option=203" rel="nofollow">square-wave anodic stripping voltammetry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemical detection&option=203" rel="nofollow">electrochemical detection;</a> </p> <div class="translation"> 机译：汞;离子印迹聚合物;聚吡咯;方波阳极溶出伏安法;电化学检测; 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