Electrochemical Properties of Polypyrrole Nanoparticles – The Role of Doping Ions and Synthesis Medium

Jaworska Ewa; Kisiel Anna; Michalska Agata; Maksymiuk Krzysztof

摘要

Abstract >Electrochemical properties of polypyrrole nanoparticles coated on glassy carbon electrodes were studied. The nanoparticles were obtained in a chemical polymerization step using a novel templateless procedure – oxidation of pyrrole released either from poly (n‐butyl acrylate) microspheres or from micelles of crosslinked alternating polymer (poly (maleic anhydride‐alt‐1‐octadecene)). Voltammetric measurements confirmed high ion transport rate inside the polymer and minor influence of the kind of doping ion and electrolyte ions present in the solution. However, electrochemical impedance spectroscopy measurements revealed a significant difference in the properties of polypyrrole nanoparticles, depending on the synthesis conditions. In case of polypyrrole synthesized in the presence of poly (n‐butyl acrylate) microspheres EIS spectra were almost independent of kind of electrolyte ions and doping anion, pointing to exposed bulk capacitive properties. On the other hand, polypyrrole nanoparticles obtained in the presence of alternating polymer micelles represent a typical constant phase element behavior with impedance significantly dependent on the kind of oxidizing (doping) anion. Due to their capacitive properties polypyrrole nanoparticles obtained in the presence of poly (n‐butyl acrylate) microspheres were applied as solid contacts in ion‐selective electrodes. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>研究了涂覆在玻璃碳电极上的聚吡咯纳米粒子的电化学性质。使用新的模特的程序 - 从聚（正丁基丙烯酸酯）微球或来自交联交替聚合物的胶束（聚（马来酸酐-Att-1-十八烯）的胶束释放的吡咯释放的吡咯的吡咯氧化纳米粒子。伏安测量确认了聚合物内的高离子传输速率和溶液中存在的掺杂离子和电解质离子的微小影响。然而，电化学阻抗光谱测量测量揭示了聚吡咯纳米粒子的性质的显着差异，这取决于合成条件。在聚（正丁基丙烯酸酯）的存在下合成的聚吡咯的情况下，EIS谱几乎独立于电解质离子和掺杂阴离子，指向暴露的散装电容性质。另一方面，在交替聚合物胶束存在下获得的聚吡咯纳米粒子代表了具有阻抗的典型恒定相的特征行为，显着取决于氧化（掺杂）阴离子的种类。由于它们的电容性，在聚（正丁基丙烯酸酯）微球存在下获得的含有聚吡咯纳米粒子作为离子选择性电极中的固体触点施加。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第4期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jaworska Ewa&option=202" target="_blank" rel="nofollow">Jaworska Ewa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kisiel Anna&option=202" target="_blank" rel="nofollow">Kisiel Anna;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Michalska Agata&option=202" target="_blank" rel="nofollow">Michalska Agata;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maksymiuk Krzysztof&option=202" target="_blank" rel="nofollow">Maksymiuk Krzysztof;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryUniversity of WarsawPasteura 1 02-093 Warsaw Poland;</p> <p>Department of ChemistryUniversity of WarsawPasteura 1 02-093 Warsaw Poland;</p> <p>Department of ChemistryUniversity of WarsawPasteura 1 02-093 Warsaw Poland;</p> <p>Department of ChemistryUniversity of WarsawPasteura 1 02-093 Warsaw Poland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electroanalytical chemistry&option=203" rel="nofollow">electroanalytical chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoparticles&option=203" rel="nofollow">nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polypyrrole&option=203" rel="nofollow">polypyrrole;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=all-solid-state ion-selective electrodes&option=203" rel="nofollow">all-solid-state ion-selective electrodes;</a> </p> <div class="translation"> 机译：电扫基化学;纳米颗粒;聚吡咯;全固态离子选择性电极; </div> </li> </ul> </div> </div> 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href="/conference-cn-9324/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第29届全国化学与物理电源学术年会 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311579748.html">掺杂聚吡咯及其复合材料的电化学合成与电化学性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李娟娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李娟娟</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061202986617.html">金属离子铜掺杂的聚氨基吡咯复合纳米粒子诊疗试剂、制备方法及其应用</a> <b>[P]</b> . <span> 中国专利： CN105854034B </span> <span> . 2018.08.24</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120108341270.html">金属离子铜掺杂的聚氨基吡咯复合纳米粒子诊疗试剂、制备方法及其应用</a> <b>[P]</b> . <span> 中国专利： CN105854034A </span> <span> . 2016-08-17</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130425027753.html">MULTIFUNCTIONAL NANOPARTICLES FOR FLUORESCENCE, MR AND PET IMAGES COMPRISING MAGNETIC SILICA NANOPARTICLES DOPED WITH A NEAR-INFRARED (NIR) DYE ALLOWING COMPOSITE IMAGING OF LYMPH NODES AND DEEP ORGANS, AND A METHOD FOR SYNTHESISING THE SAME</a> <b>[P]</b> . <span> 外国专利：  WO2011010848A2 </span> <span> . 2011-01-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于荧光，MR和PET图像的多功能纳米粒子，其包含掺杂有近红外（NIR）染料的磁性二氧化硅纳米粒子，允许对淋巴结和深层有机物进行复合成像，以及一种用于合成该纳米粒子的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130425027752.html">MULTIFUNCTIONAL NANOPARTICLES FOR FLUORESCENCE, MR AND PET IMAGES COMPRISING MAGNETIC SILICA NANOPARTICLES DOPED WITH A NEAR-INFRARED (NIR) DYE ALLOWING COMPOSITE IMAGING OF LYMPH NODES AND DEEP ORGANS, AND A METHOD FOR SYNTHESISING THE SAME</a> <b>[P]</b> . <span> 外国专利：  WO2011010848A3 </span> <span> . 2011-06-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于荧光，MR和PET图像的多功能纳米粒子，其包含掺杂有近红外（NIR）染料的磁性二氧化硅纳米粒子，允许对淋巴结和深层有机物进行复合成像，以及一种用于合成该纳米粒子的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130425027751.html">MULTIFUNCTIONAL NANOPARTICLES FOR FLUORESCENCE, MR AND PET IMAGES COMPRISING MAGNETIC SILICA NANOPARTICLES DOPED WITH A NEAR-INFRARED (NIR) DYE ALLOWING COMPOSITE IMAGING OF LYMPH NODES AND DEEP ORGANS, AND A METHOD FOR SYNTHESISING THE SAME</a> <b>[P]</b> . <span> 外国专利：  WO2011010848A9 </span> <span> . 2011-05-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> 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