Sensitive Amperometric Determination of Thiocyanates at Ionic Liquid Nanohybrid Kaolinite Modified Glassy Carbon Electrode

Nguelo Bruno Boniface; Dedzo Gustave Kenne; Tonle Ignas Kenfack; Detellier Christian; Ngameni Emmanuel

摘要

Abstract > Electrochemical sensors have been developed by modifying a glassy carbon electrode with organo‐kaolinite hybrid materials. These materials were obtained by the grafting of four ionic liquids (1‐(2‐hydroxyethyl)‐4‐benzylpyridinium chloride, 1‐(2‐hydroxyethyl)‐4‐(tert‐butyl)pyridinium chloride, 1‐(2‐hydroxyethyl)‐4‐ethylpyridinium chloride and 1‐(2‐hydroxyethyl)‐4‐methylpyridinium chloride) on the interlayer aluminol surfaces of kaolinite. With the presence of ionic liquids in the interlayer space of kaolinite, the hybrid materials acquired anion exchange properties and were successfully applied as electrode modifier for the electroanalysis of thiocyanate (SCN ? ), an anion of medical and environmental concern. A pre‐concentration/detection strategy was used to overcome the interfering effect of the electrolytic solution. After the optimisation of some key experimental parameters (sodium nitrate as electrolyte, 5?min of accumulation time) calibration curves were plotted. Excellent linearity was obtained in the low concentration region (1×10 ?6 ?M to 4×10 ?5 ?M). The lowest detection limit (15?nM) was obtained with the benzylpyridinium functionalized kaolinite and the highest (60?nM) with the methylpyridinium functionalized kaolinite. Interfering anions (NO <sub>3</sub> ? , Cl ? , SO <sub>4</sub> 2? and CH <sub>3</sub> COO ? ) present in the pre‐concentration solution were found to interfere with SCN ? but the sensors remained stable and produced reproducible signals. The most sensitive sensor was successfully applied for the amperometric determination of SCN ? </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</标题> >通过用有机高岭石混合材料改变玻璃碳电极来开发电化学传感器。通过嫁接四种离子液体（1-（2-羟乙基）-4-苄基吡啶鎓氯化吡啶，1-（2-羟乙基）-4-（叔丁基）吡啶氯化吡啶，1-（2-羟基乙基）获得。高岭土中间铝醇表面上的-4-乙基吡啶氯化啶和1-（2-羟乙基）-4-甲基吡啶鎓氯化物。随着高岭石的层间空间存在离子液体，杂化材料获得了AION交换特性，并成功地用作硫氰酸酯（SCN <SUP> </ SUP>）的电解的电极改性剂，是医疗和环境的阴离子忧虑。使用预浓度/检测策略来克服电解液的干扰效果。优化一些关键实验参数（硝酸钠作为电解质，累积时间的5〜min）绘制校准曲线。在低浓度区域（1×10 Δ6）中获得优异的线性度（1×10 Δ6至4×10 Δ5</ sup>μ）。用苄基吡啶官能化高岭石和最高（60μm）获得的最低检测限（15≤nm），具有甲基吡啶官能化高岭石。干扰阴离子（NO <sub> 3 </ sub> ？</ sup>，cl ？</ sup>，SO <sub> 4 </ sub> 2？和发现在预浓度溶液中存在的CH <sub> 3 </ sub> COO β</ sup>）将SCN <SUP>α→</ sup>干扰，但传感器保持稳定并产生可重复的信号。最敏感的传感器成功地应用于SCN <SUP>的凹部测定> </ sup> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nguelo Bruno Boniface&option=202" target="_blank" rel="nofollow">Nguelo Bruno Boniface;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dedzo Gustave Kenne&option=202" target="_blank" rel="nofollow">Dedzo Gustave Kenne;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tonle Ignas Kenfack&option=202" target="_blank" rel="nofollow">Tonle Ignas Kenfack;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Detellier Christian&option=202" target="_blank" rel="nofollow">Detellier Christian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ngameni Emmanuel&option=202" target="_blank" rel="nofollow">Ngameni Emmanuel;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Laboratoire de Chimie Analytique Faculté des SciencesUniversité de Yaoundé 1B.P. 812 Yaoundé Cameroun;</p> <p>Laboratoire de Chimie Analytique Faculté des SciencesUniversité de Yaoundé 1B.P. 812 Yaoundé Cameroun;</p> <p>Laboratoire de Chimie Analytique Faculté des SciencesUniversité de Yaoundé 1B.P. 812 Yaoundé Cameroun;</p> <p>Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and InnovationUniversity of OttawaOntario K1N 6N5 Canada;</p> <p>Laboratoire de Chimie Analytique Faculté des SciencesUniversité de Yaoundé 1B.P. 812 Yaoundé Cameroun;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Organo-kaolinite hybrids&option=203" rel="nofollow">Organo-kaolinite hybrids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ionic liquids&option=203" rel="nofollow">Ionic liquids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Electrochemical sensors&option=203" rel="nofollow">Electrochemical sensors;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thiocyanate&option=203" rel="nofollow">Thiocyanate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Human saliva&option=203" rel="nofollow">Human saliva;</a> </p> <div class="translation"> 机译：有机高岭石杂交种;离子液体;电化学传感器;硫氰酸酯;人类唾液; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023174407.html">Sensitive Amperometric Determination of Thiocyanates at Ionic Liquid Nanohybrid Kaolinite Modified Glassy Carbon Electrode</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nguelo Bruno Boniface&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nguelo Bruno Boniface,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dedzo Gustave Kenne&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dedzo Gustave Kenne,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tonle Ignas Kenfack&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tonle Ignas Kenfack,</a> <a href="/journal-foreign-22546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Electroanalysis .</a> <span>2018</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：离子液体纳米含磷酸盐改性玻碳电极硫氰酸酯的敏感功率测定</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018320013.html">Sensitive voltammetric determination of chloramphenicol by using single-wall carbon nanotube–gold nanoparticle–ionic liquid composite film modified glassy carbon electrodes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fei Xiao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fei Xiao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Faqiong Zhao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Faqiong Zhao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiangwen Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jiangwen Li,</a> <a href="/journal-foreign-19036/" target="_blank" rel="nofollow" class="tuijian_authcolor">Analytica chimica acta .</a> <span>2007</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：单壁碳纳米管-金纳米粒子-离子液体复合膜修饰玻碳电极灵敏伏安法测定氯霉素</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020679260.html">A highly selective and sensitive voltammetric sensor with molecularly imprinted polymer based silver@gold nanoparticles/ionic liquid modified glassy carbon electrode for determination of ceftizoxime</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Murat Beytur&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Murat Beytur,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Faruk Karda?&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Faruk Karda?,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Onur Aky?ld?r?m&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Onur Aky?ld?r?m,</a> <a href="/journal-foreign-35144/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Molecular Liquids .</a> <span>2018</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有分子印迹聚合物基银@金纳米颗粒/离子液体改性玻璃电极的高精度和敏感的伏安传感器，用于测定切根肟</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-277716_thesis/0705013715789.html">Amperometric determination of dopamine N-doped graphene/Au@Pt core-shell nanoparticles modified glassy carbon electrode</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xianlan Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xianlan Chen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guowei Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guowei Zhang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ling Shi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ling Shi,</a> <a href="/conference-foreign-277716/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Advanced Design and Manufacturing Engineering .</a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：多巴胺N-掺杂石墨烯/ Au @ Pt核 - 壳纳米粒子改性玻碳电极的测定测定</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061203374.html">Modified electrodes for amperometric determination of glucose and glutamate using mediated electron transport.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Harper, Alice C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Harper, Alice C. </a> <span>2005</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：修饰的电极，用于通过介导的电子传输安培测定葡萄糖和谷氨酸。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040007130220.html">Sensitive determination of hydrazine using poly(phenolphthalein) Au nanoparticles and multiwalled carbon nanotubes modified glassy carbon electrode</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Müge HATİP&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Müge HATİP,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Süleyman KOÇAK&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Süleyman KOÇAK,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zekerya DURSUN&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zekerya DURSUN </a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用聚（酚酞）Au纳米粒子和多壁碳纳米管改性玻碳电极的敏感测定</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000124946361.html">Carbon-black-doped Polyimide-modified Glassy Carbon Electrode for Sensitive Nonenzymatic Amperometric Determination of Hydrogen Peroxide</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yue Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yue Wang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lin Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lin Chen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yan Zhang,</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于敏感的非酶的聚酰亚胺改性玻碳电极用于敏感的非酶的过氧化氢测定</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_physical-testing-chemical-analysis-part-bchemical-analysis_thesis/0201212528773.html">单壁碳纳米管-纳米金-离子液体修饰玻碳电极用于线性伏安法测定辛硫磷</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘拥军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘拥军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王光灿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王光灿</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=师真&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,师真</a> <span> <a href="/journal-cn-7677/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 理化检验-化学分册 </a> </span> <span> . 2012</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_physical-testing-chemical-analysis-part-bchemical-analysis_thesis/0201212577327.html">基于碳纳米管和离子液体复合物修饰玻碳电极电催化测定己烯雌酚</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陶菡&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陶菡</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张义明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张义明</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张学俊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张学俊</a> <span> <a href="/journal-cn-7677/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 理化检验-化学分册 </a> </span> <span> . 2009</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_shandong-chemical-industry_thesis/0201275757264.html">恒电位沉积纳米Ag修饰的玻碳电极测定环境中的污染物硫离子</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曹阳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 曹阳</a> <span> <a href="/journal-cn-9186/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 山东化工 </a> </span> <span> . 2019</span><span>,第021期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_physical-testing-chemical-analysis-part-bchemical-analysis_thesis/0201212555531.html">用稀土(镱)杂多酸盐/多壁碳纳米管修饰的玻碳电极测定亚硝酸根</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗宿星&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 罗宿星</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=伍远辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,伍远辉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=勾华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,勾华</a> <span> <a href="/journal-cn-7677/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 理化检验-化学分册 </a> </span> <span> . 2010</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_metallic-ore-dressing-abroad_thesis/0201217129986.html">用电化学阻抗光谱法测定二硫代碳酸盐和三硫代碳酸盐与黄铁矿和铜的作用机理</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=J·A·文特&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . J·A·文特</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李长根&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李长根</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔洪山&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,崔洪山</a> <span> <a href="/journal-cn-7847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 国外金属矿选矿 </a> </span> <span> . 2008</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-39312_thesis/020222422563.html">离子液体-石墨烯/碳纳米管-管尖固相萃取-液相色谱法测定尿样中(顺)-3-(氯代亚甲基)-6-氟-硫色满-4-酮</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈欢欢&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈欢欢</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苑亚楠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,苑亚楠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=闫宏远&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,闫宏远</a> <span> <a href="/conference-cn-39312/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第四届环渤海色谱质谱学术报告会 </a> <span> <span> . 2016</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316266526.html">导热填料改性含磷氰酸酯阻燃树脂的制备及性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姚璐璐&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 姚璐璐</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204765293.html">一种离子液体改性蒙脱土修饰的玻碳电极及制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN110361435B </span> <span> . 2021.11.09</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101291708.html">一种离子液体改性蒙脱土修饰的玻碳电极及制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN110361435A </span> <span> . 2019-10-22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130406084206.html">/ / METHOD FOR PREPARING MULTIWALLED CARBON NANOTUBES/IONIC LIQUID/MANGANESE NANOHYBRID AND HYDROGEN GENERATION CATALYST BY THE METHOD</a> <b>[P]</b> . <span> 外国专利：  KR101803738B1 </span> <span> . 2017-12-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：//制备该方法的多元碳纳米管/离子液体/锰纳米氢和加氢催化剂的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130411429307.html">METHOD FOR PREPARING MULTIWALLED CARBON NANOTUBE/IONIC LIQUID/MANGANESE NANOHYBRID AND HYDROGEN PRODUCTION CATALYST PREPARED BY METHOD</a> <b>[P]</b> . <span> 外国专利：  KR20160127683A </span> <span> . 2016-11-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：方法制备多壁碳纳米管/离子液体/锰纳米杂化和制氢催化剂的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130421753862.html">Rubber mixture, useful for manufacturing technical rubber article, preferably straps, comprises a polar or non-polar rubber and a carbon black and an ionic liquid and/or a carbon black modified with an ionic liquid, and further additives</a> <b>[P]</b> . <span> 外国专利：  DE102011001658A1 </span> <span> . 2012-10-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：可用于制造工业橡胶制品（优选带）的橡胶混合物包含极性或非极性橡胶，炭黑和离子液体和/或经离子液体改性的炭黑，以及其他添加剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023174407','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704023174407down" data-source="7," data-out-id="YTFGGI/cs0zvl8GmJInw+aK0vyokus834kxwrhorcxrColYSnXjLFpU1zgxKNwpR," data-f-source-id="7" data-title="Sensitive Amperometric Determination of Thiocyanates at Ionic Liquid Nanohybrid Kaolinite Modified Glassy Carbon Electrode" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="22546" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Sensitive Amperometric Determination of Thiocyanates at Ionic Liquid Nanohybrid Kaolinite Modified Glassy Carbon Electrode"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>