Spectroelectrochemical Sensor for Spectroscopically Hard‐to‐detect Metals by        <i >in situin situ        Formation of a Luminescent Complex Using Ru(II) as a Model Compound

Lines Amanda M.; Warner Joshua D.; Heineman William R.; Clark Sue B.; Bryan Samuel A.

摘要

Abstract > Fast, robust, and cost‐effective means of detecting spectroscopically inactive metal species are necessary for field detection and applications within a variety of areas including industry and the nuclear safeguards fields. A sensor based on spectroelectrochemistry is an excellent candidate to meet these needs as it provides improved selectivity for specifically quantifying metal ions by simultaneously monitoring at least two physio‐chemical properties. Ruthenium was chosen as a model system for this study due to its spectroscopic and electrochemical characteristics as well as its relevance within the fuel cycle and industrial fields. Aqueous Ru displays multiple redox couples in which all available oxidation states have poor sensitivity for detection by visible absorption spectroscopy because of the low molar absorptivities. Ru can, however, form complexes with sensitizing ligands such as 2,2′‐bipyridine, where the resulting [Ru(ligand) <sub>3</sub> ] 2+ complex displays a red luminescence with a high quantum yield of emission. This significantly improves detection limits for Ru and allows for the spectroelectrochemical detection of the otherwise hard‐to‐detect metal ion. This work explores the in‐situ generation of Ru(bpy) <sub>3</sub> complexes in simulated field samples and their subsequent spectroelectrochemical sensing using our sensor methodology. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ tits> >检测光谱上不活性金属物种的快速，鲁棒和经济效益手段对于字段是必要的在各种区域内的检测和应用包括行业和核保护领域。基于光谱电化学的传感器是满足这些需求的优异候选者，因为它提供了通过同时监测至少两个物理化学性质的特异性定量金属离子的改善的选择性。由于其光谱和电化学特性以及其在燃料循环和工业领域内的相关性，选择了钌作为本研究的模型系统。 ru显示出多种氧化还原型循环，其中所有可用的氧化状态由于低摩尔吸收性而通过可见吸收光谱检测较差的敏感性。然而，ru可以形成致敏配体，如2,2'-吡啶的配合物，其中所得[Ru（配体）<亚> 3 </ sub>] 2 + / sup>复合物显示器显示红色发光具有高量子发射产量。这显着改善了Ru的检测限，并且允许否则难以检测的金属离子的光谱电化学检测。这项工作探讨了使用我们的传感器方法的模拟场样本中的ru（bpy）<sub> 3 </ sub>复合物的原位生成及其随后的光谱电化学传感。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第11期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lines Amanda M.&option=202" target="_blank" rel="nofollow">Lines Amanda M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Warner Joshua D.&option=202" target="_blank" rel="nofollow">Warner Joshua D.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heineman William R.&option=202" target="_blank" rel="nofollow">Heineman William R.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Clark Sue B.&option=202" target="_blank" rel="nofollow">Clark Sue B.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bryan Samuel A.&option=202" target="_blank" rel="nofollow">Bryan Samuel A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Energy and Environment DirectoratePacific Northwest National LaboratoryRichland WA 99352;</p> <p>Energy and Environment DirectoratePacific Northwest National LaboratoryRichland WA 99352;</p> <p>Department of ChemistryUniversity of CincinnatiCincinnati OH 45221;</p> <p>Energy and Environment DirectoratePacific Northwest National LaboratoryRichland WA 99352;</p> <p>Energy and Environment DirectoratePacific Northwest National LaboratoryRichland WA 99352;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Spectroelectrochemistry&option=203" rel="nofollow">Spectroelectrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sensor&option=203" rel="nofollow">Sensor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ruthenium&option=203" rel="nofollow">Ruthenium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=2&option=203" rel="nofollow">2;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=2′-bipyridine&option=203" rel="nofollow">2′-bipyridine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luminescence&option=203" rel="nofollow">Luminescence;</a> </p> <div class="translation"> 机译：光谱电化学;传感器;钌;2;2'-硼吡啶;发光; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023174452.html">Cover Feature: Spectroelectrochemical Sensor for Spectroscopically Hard‐to‐detect Metals by <i >in situin situ Formation of a Luminescent Complex Using Ru(II) as a Model Compound (Electroanalysis 11/2018)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lines Amanda M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lines Amanda M.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Warner Joshua D.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Warner Joshua D.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heineman William R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Heineman William R.,</a> <a href="/journal-foreign-22546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Electroanalysis .</a> <span>2018</span><span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：覆盖特征：用于光谱电化学传感器，通过使用Ru（ii）作为模型化合物的发光复合物原位形成的光谱电化学传感器，其原位形成发光络合物（电催化11/2018）</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704015834674.html">METAL COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .87. ALPHA-AMINO CARBOXYLATE COMPLEXES OF PALLADIUM(II), IRIDIUM(III) AND RUTHENIUM(II) FROM CHLORO-BRIDGED ORTHO-METALLATED METAL COMPOUNDS AND [(OC)(3)RU(CL)(MU-CL)](2)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Urban R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Urban R.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mihan S.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mihan S.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Polborn K.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Polborn K.,</a> <a href="/journal-foreign-36456/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Organometallic Chemistry .</a> <span>1996</span><span>,第1a2期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：生物重要配体的金属配合物.87。氯桥键金属杂化化合物和[（OC）（3）RU（CL）（MU-CL）]（2）中钯（II），铱（III）和钌（II）的α-氨基羧酸盐络合物</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070407602582.html">Strongly luminescent metal-organic compounds: spectroscopic properties and crystal structure of substituted 1,8-naphthyridine and its zinc(II) complex</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Che CM.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Che CM.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ho KY.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ho KY.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou ZY.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhou ZY.,</a> <a href="/journal-foreign-25889/" target="_blank" rel="nofollow" class="tuijian_authcolor">New Journal of Chemistry .</a> <span>2001</span><span>,第1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：强发光金属-有机化合物：取代的1,8-萘啶及其锌（II）配合物的光谱性质和晶体结构</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-264625_thesis/0705011894605.html">Spectroscopic Characterisation of Luminescent Eu (III)/Polyoxometalate Sandwiched and Encrypted Complexes</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S.Lis&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">S.Lis,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S.But&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">S.But </a> <a href="/conference-foreign-264625/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Rare Earths .</a> <span>1999</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：发光EU（III）/聚氧酸盐夹层和加密复合物的光谱表征</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061708252.html">Synthetic, structural, and spectroscopic study of luminescent transition metal complexes for use in electronic devices and environmental sensors</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=McGee, Kari Ann&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">McGee, Kari Ann </a> <span>2008</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于电子设备和环境传感器的发光过渡金属配合物的合成，结构和光谱研究</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_metal-based-drugs_thesis/040001721780.html">Studies on Some New Ru(III) Complexes Using aryl-azo Pentane-2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands:Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lallan Mishra&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lallan Mishra,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ajay K. Yadaw&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ajay K. Yadaw,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ratna S. Phadke&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ratna S. Phadke,</a> <span>1947</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100055823457.html">Strongly luminescent metal–organic compounds: spectroscopic properties and crystal structure of substituted 1,8-naphthyridine and its zinc(II) complex</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Che CM&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Che CM,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wan CW&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wan CW,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ho KY&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ho KY,</a> <span>2001</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：强发光金属-有机化合物：取代的1,8-萘啶及其锌（II）配合物的光谱性质和晶体结构</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-instrumental-analysis_thesis/0201230483195.html">基于原位形成p-n结的新型光电化学传感器检测Hg2+</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘康丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘康丽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=董玉明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,董玉明</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=束军仙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,束军仙</a> <span> <a href="/journal-cn-10803/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析测试学报 </a> </span> <span> . 2014</span><span>,第008期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201294007204.html">金属离子在液相氧化中的催化作用——Ⅹ.过渡金属氯化物与简单配体原位形成的配合物在环己烯氧化反应中的催化作用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=叶兴凯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 叶兴凯</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苏为平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,苏为平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马建伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马建伟</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 无机化学学报 </a> </span> <span> . 1993</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201275748277.html">漫透射光谱电化学原位研究穿梭体介导的胞外电子传递过程</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴苗&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吴苗</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2019</span><span>,第014期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-instrumental-analysis_thesis/0201230485038.html">邻氨基酚与邻苯二胺共聚的原位紫外-可见光谱电化学研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐文茹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐文茹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张雷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张雷</a> <span> <a href="/journal-cn-10803/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析测试学报 </a> </span> <span> . 2014</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-shanghai-normal-university-natural-sciences_thesis/0201248694627.html">银电极上N-(4,6-二甲氧嘧啶-2-基)-N'-β-吡啶甲酰基硫脲的原位SERS光谱电化学研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=金乔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 金乔</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=沈姝&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,沈姝</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈颖萍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈颖萍</a> <span> <a href="/journal-cn-4565/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 上海师范大学学报（自然科学版） </a> </span> <span> . 2014</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-59371_thesis/020222599374.html">变温流动原位光谱电解池的研制和初步光谱电化学研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=连小兵&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 连小兵</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赖群萍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赖群萍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=方萍萍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,方萍萍</a> <span> <a href="/conference-cn-59371/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十四次全国电化学会议 </a> <span> <span> . 2007</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311533870.html">轻烷选择氧化氧物种和反应机理的原位Raman光谱表征Ⅰ：LaO上过氧及相关氧物种激光诱导生成的原位Raman光谱表征;Ⅱ：SiO和AlO负载的Ru、Rh和Ir催化剂上甲烷部分氧化制合成气反应的原位Raman光谱表征</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李建梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李建梅</a> <span> . 2008</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120106743465.html">和频光谱原位流动薄层光谱电化学反应池</a> <b>[P]</b> . <span> 中国专利： CN102539328A </span> <span> . 2012-07-04</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104645047.html">使用原位形成的后过渡金属催化剂配合物的聚合</a> <b>[P]</b> . <span> 中国专利： CN1447717A </span> <span> . 2003-10-08</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130403834880.html">New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials</a> <b>[P]</b> . <span> 外国专利：  PL422434A1 </span> <span> . 2019-02-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新光引发体系，new的新络合物（III）及其制备方法，application的络合物的应用，用于监测聚合的新型发光分子探针工艺，用于涂层材料测试的新型发光分子传感器 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403835196.html">New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials</a> <b>[P]</b> . <span> 外国专利：  PL421951A1 </span> <span> . 2019-01-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新光引发体系，new的新配合物（III）及其生产方法，applications的配合物（III）的应用，用于监测聚合反应的新型发光分子探针工艺，用于涂层材料测试的新型发光分子传感器 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403835023.html">New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials</a> <b>[P]</b> . <span> 外国专利：  PL422386A1 </span> <span> . 2019-02-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于光引发的阳离子，自由基，硫醇-烯和杂化聚合过程的新光引发体系，new的新络合物（III）及其制备方法，application的络合物的应用（III），用于监测氟的新型发光分子探针聚合工艺，用于涂层材料测试的新型发光分子传感器 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023174567','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704023174567down" data-source="7," data-out-id="i6wUJjkEkEHFILpDtj060zWwTy5ZmgiOVfmcf+pKlDj4GBEwu/nKq2aF8PAd8KB6," data-f-source-id="7" data-title="Spectroelectrochemical Sensor for Spectroscopically Hard‐to‐detect Metals by <i >in situin situ Formation of a Luminescent Complex Using Ru(II) as a Model Compound" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="22546" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Spectroelectrochemical Sensor for Spectroscopically Hard‐to‐detect Metals by <i >in situin situ Formation of a Luminescent Complex Using Ru(II) as a Model Compound"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>

Spectroelectrochemical Sensor for Spectroscopically Hard‐to‐detect Metals by in situin situ Formation of a Luminescent Complex Using Ru(II) as a Model Compound

摘要