A Sensitive Electrochemical Sensor for Voltammetric Determination of Ganciclovir Based on Au‐ZnS Nanocomposite

Yari Abdollah; Shams Azim

摘要

Abstract >An electrode modified with ZnS and gold nanoparticles (Au‐ZnS NPs) is introduced for highly sensitive voltammetric determination of ganciclovir (GCV). Surface structure and topography of the modified electrode was studied by SEM, EDX and XRD techniques. Electrochemical oxidation of GCV was investigated by cyclic (CV) and square wave voltammetry (SWV) in Briton‐Robinson buffer solution (pH?1.5). The results showed that electrochemical oxidation of GCV at the Au‐ZnS modified glassy carbon electrode (GCE) is irreversible and exhibited diffusion controlled electrode process over the pH range from 1.0 to 6.0. The oxidation potential peak and pH relationship showed that electrons and protons were transferred simultaneously over the electrochemical oxidation process. Using the proposed sensor, the linear calibration curves were obtained in the ranges of 0.04–1.50?μM and 1.5–70.0?μM with detection limit of 0.01?μM GCV by SWV technique. The modified electrode was successfully applied as a sensitive, reproducible and repeatable sensor for determination of the trace amount of GCV in human serum, urine and cymevene vials. Reasonable results were obtained from comparing the measurements of the real samples by the new sensor to high performance liquid chromatography (HPLC) as a standard method. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >用ZnS和金纳米颗粒（AU-ZnS NPS）改装的电极进行高度敏感伏安测定Ganciclovir（GCV）。通过SEM，EDX和XRD技术研究了改性电极的表面结构和地形。通过在英国 - 罗宾逊缓冲溶液（pH≤1.5）中，通过环状（CV）和方波伏安法（SWV）研究了GCV的电化学氧化（pH？1.5）。结果表明，Au-ZnS改性玻璃电极（GCE）的GCV的电化学氧化是不可逆转的，并且在pH范围为1.0至6.0的延伸控制电极工艺。氧化电位峰和pH值表明，在电化学氧化过程上同时转移电子和质子。使用所提出的传感器，在0.04-1.50Ωμm和1.5-70.0Ωμm的范围内获得线性校准曲线，通过SWV技术检测极限为0.01ΩμmGCV。改性电极被成功地用作敏感，可重复和可重复的传感器，用于测定人血清，尿液和Cyhevene小瓶中的痕量GCV。获得合理的结果是通过将新传感器的真实样品的测量值与高性能液相色谱（HPLC）进行比较，作为标准方法。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第5期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yari Abdollah&option=202" target="_blank" rel="nofollow">Yari Abdollah;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shams Azim&option=202" target="_blank" rel="nofollow">Shams Azim;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of analytical chemistryLorestan University68137-17133 Khorramabad – Iran;</p> <p>Department of analytical chemistryLorestan University68137-17133 Khorramabad – Iran;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Au-ZnS nanocomposite&option=203" rel="nofollow">Au-ZnS nanocomposite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ganciclovir&option=203" rel="nofollow">Ganciclovir;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Modified electrode&option=203" rel="nofollow">Modified electrode;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ZnS nanoparticle&option=203" rel="nofollow">ZnS nanoparticle;</a> </p> <div class="translation"> 机译：Au-ZnS纳米复合材料;Ganciclovir;改性电极;ZnS纳米粒子; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023174588.html">A Sensitive Electrochemical Sensor for 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href="/patent-detail/06120103937927.html">基于快速扫描循环伏安技术检测铅离子的电化学传感器的制备方法及其应用</a> <b>[P]</b> . <span> 中国专利： CN111307917A </span> <span> . 2020-06-19</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061204195312.html">基于氮硫共掺杂石墨烯负载三角核壳纳米复合材料构建的电化学传感器及用于槲皮素的检测</a> <b>[P]</b> . <span> 中国专利： CN109187691B </span> <span> . 2021.01.08</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130425401244.html">ELECTROCHEMICAL BIOSENSOR FOR SIMULTANEOUS DETERMINATION OF SUPEROXIDE ANION RADICAL AND NITRITE USING CU, ZNSOD IMMOBILIZED ON HYBRID GOLD NANOPARTICLES/CARBON NANOTUBES IN CONDUCTING POLYMER NANOCOMPOSITE</a> <b>[P]</b> . <span> 外国专利：  IN2010CH00668A </span> <span> . 2011-09-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电化学生物传感器同时测定混合金纳米粒子/碳纳米管中固定化的铜，ZNSOD铜，同时测定聚合物纳米复合材料中的过氧化阴离子自由基和亚硝酸根 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130400742077.html">- Zn / - Zn Hybrid Nanomaterials containing dendritic fibrous nanosilica core - Zn-based coordination polymers shell or dendritic fibrous nanosilica/Au core - Zn-based coordination polymers shell a synthetic method thereof and applications of the nanomaterials</a> <b>[P]</b> . <span> 外国专利：  KR20200049966A </span> <span> . 2020-05-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-含有树状纤维纳米二氧化硅核的Zn / -Zn杂化纳米材料-Zn基配位聚合物壳或树状纤维纳米二氧化硅/ Au核-Zn基配位聚合物壳的合成方法及其在纳米材料中的应用 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130499967267.html">Hybrid Nanomaterials containing dendritic fibrous nanosilica core - Zn-based coordination polymers shell or dendritic fibrous nanosilica/Au core - Zn-based coordination polymers shell, a synthetic method thereof and applications of the nanomaterials</a> <b>[P]</b> . <span> 外国专利：  KR102246615B1 </span> <span> . 2021-05-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含有树枝状纤维型核心 - 锌的配位聚合物壳或树突式纤维纳米硅/ Au核 - Zn的配位聚合物壳，其合成方法及纳米材料的应用及纳米材料的杂交纳米材料 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023174588','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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