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Growth of Self‐Assembling Tubular Structures of Magnesium Oxy/Hydroxide and Silicate Related With Seafloor Hydrothermal Systems Driven by Serpentinization

机译:氧化镁和硅酸盐和硅酸盐的自组装管状结构的生长与由锯齿化驱动的海底热水系统相关

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Abstract >Tubular structures self‐assemble from precipitating magnesium salts under the chemical garden chemobrionic growth process. Two experimental procedures, the dissolution of magnesium salt pellets and the injection of magnesium salt solutions into silicate solutions, were explored to reproduce in the laboratory the geochemical conditions under which similar structures may form from mineral‐rich fluids at some seafloor hydrothermal vents driven by serpentinization. X‐ray diffraction and Raman microspectroscopy applied to the materials formed indicated the presence of layers of magnesium silicate and magnesium oxide/hydroxide. Quantum mechanical calculations based on density functional theory were performed on models of hydrated magnesium silicate surfaces and related minerals to explain the Raman spectroscopy results. We examine the precipitate morphology, chemical structure, and crystal or mineral structure in our experiments and how these change with the reaction conditions. This is a fascinating example in geochemistry of a self‐organizing nonequilibrium process that creates complex structures. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“main”XML:Lang =“en”XML:ID =“GGGE21647-ABS-ABS-ABS-0001”> <标题类型=“main”>抽象</ title> >管状结构自组装在化学园化化学生长过程下沉淀镁盐。两种实验程序,镁盐颗粒的溶解和将镁盐溶液注射到硅酸盐溶液中,在实验室中繁殖,在实验室中繁殖,在该地球化学条件下,在由蛇形化驱动的一些海底水热通风口中可以形成类似的结构的地球化学条件。应用于形成的材料的X射线衍射和拉曼微穴位检查表明存在层硅酸镁层和氧化镁/氢氧化物。基于密度泛函理论的量子力学计算对水合硅酸盐表面和相关矿物质的模型进行了解释了拉曼光谱结果。我们在我们的实验中检查沉淀物形态,化学结构和晶体或矿物结构,以及这些变化如何随反应条件。这是一个令人振奋的地球化学的迷人示例,其自组织非识别过程产生复杂结构。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-23285/'>《Geochemistry, geophysics, geosystems》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sainz‐Díaz C. Ignacio&option=202" target="_blank" rel="nofollow">Sainz‐Díaz C. Ignacio;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Escamilla‐Roa Elizabeth&option=202" target="_blank" rel="nofollow">Escamilla‐Roa Elizabeth;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cartwright Julyan H. E.&option=202" target="_blank" rel="nofollow">Cartwright Julyan H. E.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Instituto Andaluz de Ciencias de la TierraCSIC‐Universidad de GranadaArmilla Spain;</p> <p>Instituto Andaluz de Ciencias de la TierraCSIC‐Universidad de GranadaArmilla Spain;</p> <p>Instituto Andaluz de Ciencias de la TierraCSIC‐Universidad de GranadaArmilla Spain;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alkaline hydrothermal vents&option=203" rel="nofollow">alkaline hydrothermal vents;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=serpentinization&option=203" rel="nofollow">serpentinization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chemical gardens&option=203" rel="nofollow">chemical gardens;</a> </p> <div class="translation"> 机译:碱性水热通风口;蛇形化;化学花园; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023360465.html">Growth of Self‐Assembling Tubular Structures of Magnesium Oxy/Hydroxide and Silicate Related With Seafloor Hydrothermal Systems Driven by Serpentinization</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sainz‐Díaz C. 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