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首页> 外文期刊>Geochemistry, geophysics, geosystems >Natural H-2 in Kansas: Deep or shallow origin?
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Natural H-2 in Kansas: Deep or shallow origin?

机译:堪萨斯州的天然H-2:深层或浅层起源?

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A geochemical study of gas coming from three wells in northeastern Kansas supplements previous studies from the 1980s and points to a persistent regional phenomenon of H-2 production. In 2008, a new well showed, just after drilling, a free gas phase with more than 80 mole % of H-2, followed by water production associated with gas. This gas is mainly composed of N-2, He, H-2, and occasionally CH4, with changing proportions through time. A drastic decrease in H-2 at the well was observed since the aquifer is produced, along with occasional recharges in H-2 evidenced notably in the early phases of gas sampling. We demonstrate that this evolution of gas composition is closely associated to the well completion story. Accordingly, two distinct origins of H-2 are proposed: (1) deep crustal H-2: water reduction associated to iron oxidation in the Precambrian basement; (2) reactions occurring in the tubing, primarily attributed to high contents of reduced iron and/or dissolved organic carbon (DOC=4.1 mg L-1) in the water. The low D values averaging -760 are attributed to a low temperature process, possibly a re-equilibration with water. Furthermore, the suggested origins are supported by the observed gas associations: (a) deep crustal H-2 with radiogenic gases (He-4 and Ar-40) and metamorphic N-2 (N-15 averaging +2.5); (b) surficial H-2 with methane produced in the sedimentary aquifer and the tubing by methanogenic organisms.
机译:从20世纪80年代的东北堪萨斯州康斯康斯康斯三井的天然气研究综合研究,并指出了H-2生产的持续区域现象。 2008年,一个新的井,刚刚在钻孔后,自由气相具有超过80摩尔%的H-2,其次是与气体相关的水。这种气体主要由N-2,HE,H-2和偶尔CH4组成,随着时间的推移而改变比例。由于产生含水层,因此观察到井中的H-2在井中的急剧下降,以及H-2的偶尔充电显着在气体取样的早期相位中证明。我们表明,这种气体组成的演变与整理故事密切相关。因此,提出了两种不同的H-2的起源:(1)深层地壳H-2:与预先印范地下室的铁氧化相关的水降低; (2)在管中发生的反应,主要归因于水中的还原铁和/或溶解的有机碳(DOC = 4.1mg L-1)中的高含量。平均-760的低D值归因于低温过程,可能与水重新平衡。此外,所提出的起源是由观察到的气体关联的支持:(a)深色地壳H-2,具有辐射性气体(He-4和Ar-40)和变质N-2(N-15平均+2.5); (b)沉积含水层中产生的甲烷的表层H-2和由甲烷生物的管道。

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