Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels

McNeice Peter; Zhao Yingying; Wang Jianxun; Donnelly Gerald F.; Marr Patricia C.

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Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels

机译：离子液体的低分子量胶凝器（LMWG）：氢键和静态在稳定低分子量离子液体凝胶中的作用

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Low molecular weight gelators capable of forming a gel with an ionic liquid are rare. We report the ability of 3 sugar based gelators from renewable resources (derived from isosorbide and mannitol) to form gels with 21 ionic liquids comprising a range of cations and anions that are commonly applied in a variety of technologies. It was found that the combined consideration of Kamlet-Taft values with ionic liquid size and shape gives a useful predictor of successful gel formation.

机译：能够用离子液体形成凝胶的低分子量凝胶剂是罕见的。我们报道了3种糖基凝胶器从可再生资源（来自异山梨醇和甘露醇）的能力，形成具有21个离子液体的凝胶，其包含一系列阳离子和阴离子，通常适用于各种技术。发现具有离子液体尺寸和形状的Kamlet-Taft值的组合考虑给出了成功凝胶形成的有用预测因子。

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《Green chemistry》 |2017年第19期|共8页
作者
McNeice Peter; Zhao Yingying; Wang Jianxun; Donnelly Gerald F.; Marr Patricia C.;
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作者单位

Queens Univ Belfast Sch Chem &

Chem Engn David Keir Bldg Stranmillis Rd Belfast BT9 5AG Antrim North Ireland;

Queens Univ Belfast Sch Chem &

Chem Engn David Keir Bldg Stranmillis Rd Belfast BT9 5AG Antrim North Ireland;

Queens Univ Belfast Sch Chem &

Chem Engn David Keir Bldg Stranmillis Rd Belfast BT9 5AG Antrim North Ireland;

Queens Univ Belfast Sch Chem &

Chem Engn David Keir Bldg Stranmillis Rd Belfast BT9 5AG Antrim North Ireland;

Queens Univ Belfast Sch Chem &

Chem Engn David Keir Bldg Stranmillis Rd Belfast BT9 5AG Antrim North Ireland;

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原文格式 PDF
正文语种 eng
中图分类环境化学;数理科学和化学;化学工业废物处理与综合利用;
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1. Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels [J] . McNeice Peter, Zhao Yingying, Wang Jianxun, Green chemistry . 2017,第19期

机译：离子液体的低分子量胶凝器（LMWG）：氢键和静态在稳定低分子量离子液体凝胶中的作用
2. Highly Conductive Ionic-Liquid Gels Prepared with Orthogonal Double Networks of a Low-Molecular-Weight Gelator and Cross-Linked Polymer [J] . Kataoka Toshikazu, Ishioka Yumi, Mizuhata Minoru, ACS applied materials & interfaces . 2015,第41期

机译：用低分子量胶凝剂和交联聚合物的正交双网制备的高导电性离子液体凝胶
3. Thermal Properties, Conductivity, and Spin-lattice Relaxation of Gel Electrolyte Based on Low Molecular Weight Gelator and Solution of High Temperature Ionic Liquid [J] . Bielejewski Michal, Puszkarska Anna, Tritt-Goc Jadwiga Electrochimica Acta . 2015,第Null期

机译：基于低分子量胶凝剂和高温离子液体溶液的凝胶电解质的热性质，电导率和自旋晶格弛豫
4. Synthesis and Physical Properties of Ionic Liquid Gels Based on Novel Low Molecular Weight Gelators [C] . Tomohiro Yoshida, Tomomi Hirakawa, Toru Nakamura, Student posters (general) - 222nd ECS meeting/PRiME 2012 . 2012

机译：基于新型低分子量胶凝剂的离子液体凝胶的合成及其物理性质
5. Supramolecular Polymeric Networks via Hydrogen Bonding in Ionic Liquids. [D] . Lei, Yu. 2012

机译：在离子液体中通过氢键键合的超分子聚合物网络。
6. Highly Stereoselective Synthesis of 16-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators [O] . Henrik Sundén, Linda Ta, Anton Axelsson 2015

机译：离子液体介导的16-酮酯的高立体选择性合成：三组分反应使快速进入新型低分子量胶凝剂成为可能
7. Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels [O] . McNeice, Peter, Zhao, Yingying, Wang,, Jianxun, 2018

机译：用于离子液体的低分子量胶凝剂（LMWG）：氢键和位阻在形成稳定的低分子量离子液体胶中的作用

Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels

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