Two new Bi(III) and Ce(III)-containing coordination complexes: Crystal structure and anticancer activity in neuroblastoma

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Two new Bi(III) and Ce(III)-containing coordination complexes: Crystal structure and anticancer activity in neuroblastoma

机译：两个新的Bi（III）和Ce（III） - 统一性配合物：神经母细胞瘤中的晶体结构和抗癌活性

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Solvothermal reactions of 2,2-bipyridine (2,2-bpy) or 1,10-phenanthroline (1,10-phen) with Bi(NO3)(3)center dot 5H(2)O or Ce(NO3)(3)center dot 6H(2)O in the presence of different pH modulator afforded two new coordination complexes [Bi-2(2,2-bpy)(2)(BA)(6)] (1, HBA = benzoic acid) and [Ce(1,10-phen)Cl-2]Cl (2). The structures of the two complexes have been characterized by elemental analysis, infrared spectrum and X-ray crystal diffraction. Furthermore, the anticancer activity of the two synthesized complexes has been evaluated via the preformation of the Cell Counting Kit-8 (CCK-8) assays. And the relative expression of the inflammatory response genes p53, nf-kappa b, and tnf-alpha was detected by reverse transcriotion-polymerase chain reaction (RT-PCR).

机译：2,2-二吡啶（2,2-BPY）或1,10菲咯啉（1,10吩）的溶剂热反应与BI（NO3）（3）中心点5H（2）O或CE（NO3）（3 ）在不同的pH调节剂存在下，中心点6h（2）o得到两个新的配位复合物[Bi-2（2,2-Bpy）（2）（2）（Ba）（3）]（1，HBA =苯甲酸）和 [Ce（1,10-phen）Cl-2] Cl（2）。两种配合物的结构已经表征了元素分析，红外光谱和X射线晶衍射。此外，已经通过细胞计数试剂盒-8（CCK-8）测定的预成形来评估两种合成复合物的抗癌活性。通过反向转铁聚聚合酶链反应（RT-PCR）检测炎症反应基因P53，NF-Kappa B和TNF-α的相对表达。

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《Main group chemistry》 |2020年第1期|共9页
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正文语种 eng
中图分类化学;
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Coordination complex; X-ray diffraction; anticancer activity; CCK-8 assay; inflammatory genes;

机译：协调复合物;X射线衍射;抗癌活动;CCK-8测定;炎症基因;

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1. Two new Bi(III) and Ce(III)-containing coordination complexes: Crystal structure and anticancer activity in neuroblastoma [J] . Main group chemistry . 2020,第1期

机译：两个新的Bi（III）和Ce（III） - 统一性配合物：神经母细胞瘤中的晶体结构和抗癌活性
2. Synthesis, structure, and anticancer activity of gallium(III) complexes with asymmetric tridentate ligands: Growth inhibition and apoptosis induction of cisplatin-resistant neuroblastoma cells [J] . Shakya R, Peng FY, Liu JG, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第16期

机译：具有不对称三齿配体的镓（III）配合物的合成，结构和抗癌活性：顺铂耐药神经母细胞瘤细胞的生长抑制和凋亡诱导
3. Two novel nanostructured La(III) coordination polymers were synthesized by sonochemical: crystal structures along with anticancer activity on human nasopharyngeal carcinoma cells [J] . Cui Zhong-Tao, Liu Hong, Yuan Yao-Wei, Journal of the Iranian Chemical Society . 2020,第9期

机译：通过SONOCHEMICAL：SONSOOPEMICAL：晶体结构与人鼻咽癌细胞的抗癌活性合成了两种新型纳米结构的LA（III）配位聚合物
4. New complexes of lanthanum La(III) and Cerium Ce(III) with bis-coumarins. Synthesis, characterization and cytotoxicity for human lymphoblastoid cells (MT-2) [C] . Kostova, I., Raleva, Workshop on Macro, Trace and Ultratrace Elements; 20040924-25; Jena(DE) . 2004

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7. Synthesis, Characterization and Solution Chemistry of trans-Indazoliumtetrachlorobis(Indazole)Ruthenate(III), a New Anticancer Ruthenium Complex. IR, UV, NMR, HPLC Investigations and Antitumor Activity. Crystal Structures of trans-1-Methyl-Indazoliumtetrachlorobis-(1-Methylindazole)Ruthenate(III) and its Hydrolysis Product trans-Monoaquatrichlorobis-(1-Methylindazole)-Ruthenate(III) [O] . Lipponer, Kari-Georg, Vogel, Ellen, Keppler, Bernhard K. 1996

机译：of的合成，表征与溶液化学。一种新型的反式吲哚四氯双（吲唑）钌（III）钌抗癌复合物。 IR，UV，NMR，HPLC研究和抗肿瘤活性。反式-1-甲基-吲唑四氯双-（1-甲基吲唑）钌的晶体结构（III）及其水解产物反-季铵三氯-（1-甲基吲唑）-钌（III）
8. Crystal-Structure Determinations of Lu sub 3 S sub 4 , Nonstoichiometric Nb sub 1 sub 06 S sub 2 , and Three Group VIII Coordination Complexes [R] . Powell, D. R. 1979

机译：Lu sub 3 s sub 4，非化学计量Nb sub 1 sub 06 s sub 2和Three VIII VIII配位化合物的晶体结构测定

Two new Bi(III) and Ce(III)-containing coordination complexes: Crystal structure and anticancer activity in neuroblastoma

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