Synthesis, crystal structure and third order nonlinear optical properties of bis(tetra-n-propylammonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)

Guo WF; Sun XB; Sun J; Yu WT; Wang XQ; Zhang GH; Xu D

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Synthesis, crystal structure and third order nonlinear optical properties of bis(tetra-n-propylammonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)

机译：双（四正丙基铵）双（2-硫代-1,3-二硫代-4,5-二硫代镧）铜酸盐的合成，晶体结构和三阶非线性光学性质（II）

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A novel his (dmit) complex of copper (II), [(C3H7)(4)N](2)[Cu(dmit)(2)] (1), where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, was prepared and structurally characterized by X-ray single crystal diffraction. The copper (11) atom is tetracoordinated by four dmit S atoms, forming a nearly square planar arrangement. The [Cu(dmit)(2)](2-) anions and the [(C3H7)(4)N](+) counter-cations form a three-dimensional solid-state structure by C-H...S hydrogen bonds. The third-order nonlinear optical properties of the complex were determined by picosecond Z-scan technique at a wavelength of 1064 nm. The results indicate the compound exhibits reverse saturation absorption and self-defocusing performance. The molecular second-order hyperpolarizability gamma is calculated to be as high as (1.8 +/- 0.2)x 10(-30) esu. (C) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

机译：一种新颖的他的（dmit）铜（II）络合物，[（C3H7）（4）N]（2）[Cu（dmit）（2）]（1），其中dmit是2-thioxo-1,3-dithiole制备了-4，5-二硫代硫酸盐，并通过X射线单晶衍射对其结构进行了表征。铜原子（11）与四个dmit S原子四配位，形成近乎正方形的平面排列。 [Cu（dmit）（2）]（2-）阴离子和[（C3H7）（4）N]（+）抗衡阳离子通过C-H ... S氢键形成三维固态结构。该复合物的三阶非线性光学性质是通过皮秒Z扫描技术在1064 nm波长处确定的。结果表明该化合物表现出反向饱和吸收和自散焦性能。计算出的分子二阶超极化率γ高达（1.8 +/- 0.2）x 10（-30）esu。（C）2007 WILEY-VCH Verlag GmbH＆Co. KGaA，Weinheim。

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来源
《Crystal Research and Technology: Journal of Experimental and Industrial Crystallography》 |2007年第5期|共7页
作者
Guo WF; Sun XB; Sun J; Yu WT; Wang XQ; Zhang GH; Xu D;
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正文语种 eng
中图分类晶体学;
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bis(dmit) complexes; crystal growth; X-ray diffraction; optical properties; 1; 3-DITHIOLE-2-THIONE-4; 5-DITHIOLATE DMIT; METAL-COMPLEXES; Z-SCAN; DITHIOLATE; CHEMISTRY;

机译：双（dmit）配合物;晶体生长;X射线衍射;光学性质;1;3-二噻吩-2-噻吩-4;5-二硫代DMIT;金属络合物;Z-扫描;二硫代;化学性质;

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Synthesis, crystal structure and third order nonlinear optical properties of bis(tetra-n-propylammonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)

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