Solubility phase diagrams of Me2SO4-NiSO4-H2O systems and the growth of Me2Ni(SO4)(2)center dot nH(2)O crystals [Me = Na, Rb, Cs; n=4, 6]

Soboleva LV

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Solubility phase diagrams of Me2SO4-NiSO4-H2O systems and the growth of Me2Ni(SO4)(2)center dot nH(2)O crystals [Me = Na, Rb, Cs; n=4, 6]

机译：Me2SO4-NiSO4-H2O系统的溶解相图和Me2Ni（SO4）（2）中心点nH（2）O晶体的生长[Me = Na，Rb，Cs; n = 4、6]

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On the basis of the physicochemical analysis of the solubility phase diagrams for the Me 2SO4-NiSO4-H2O ternary systems (Me = Na, Rb, or Cs), the optimum concentration and temperature conditions for the crystallization of the Me Ni-2(SO4)(2) center dot nH(2)O solid phases were found. Techniques for growth of single crystals of these binary salts have been developed. Such techniques allow application of mother liquors containing hydrates or anhydrous sulfates of Na, Rb, Cs, and Ni as raw materials. Na2Ni(SO4)(2) center dot 4H(2)O, Rb2Ni(SO4)(2) center dot 6H(2)O, and Cs2Ni(SO4)(2) center dot 6H(2)O single crystals (28-34) x (8-13) x (5-10) mm(3) in size have been grown from aqueous solutions in the dynamic regime.

机译：根据Me 2SO4-NiSO4-H2O三元体系（Me = Na，Rb或Cs）的溶解度相图的理化分析，确定了Me Ni-2（SO4）结晶的最佳浓度和温度条件）（2）中心点nH（2）O固相被发现。已经开发了用于生长这些二元盐的单晶的技术。这样的技术允许使用含有Na，Rb，Cs和Ni的水合物或无水硫酸盐的母液作为原料。 Na2Ni（SO4）（2）中心点4H（2）O，Rb2Ni（SO4）（2）中心点6H（2）O和Cs2Ni（SO4）（2）中心点6H（2）O单晶（28- 34）x（8-13）x（5-10）mm（3）的大小已在动态范围内从水溶液中生长出来。

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《Crystallography reports》 |2007年第6期|共4页
作者
Soboleva LV;
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正文语种 eng
中图分类晶体学;
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NI; CO;

机译：NI;CO;

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1. Solubility phase diagrams of Me2SO4-NiSO4-H2O systems and the growth of Me2Ni(SO4)(2)center dot nH(2)O crystals [Me = Na, Rb, Cs; n=4, 6] [J] . Soboleva LV Crystallography reports . 2007,第6期

机译：Me2SO4-NiSO4-H2O系统的溶解相图和Me2Ni（SO4）（2）中心点nH（2）O晶体的生长[Me = Na，Rb，Cs; n = 4、6]
2. Compositions of supersaturated solutions for enhanced growth of alpha-NiSO4 center dot 6H(2)O, Me2Ni(SO4)(2) center dot 6H(2)O, MeH2PO4 [Me = Li, Na, K, Rb, Cs, NH4], and K(HxD1-x)(2)PO4 single crystals [J] . Soboleva LV Crystallography reports . 2008,第3期

机译：用于增强α-NiSO4中心点6H（2）O，Me2Ni（SO4）（2）中心点6H（2）O，MeH2PO4增长的过饱和溶液的组成[Me = Li，Na，K，Rb，Cs，NH4]和K（HxD1-x）（2）PO4单晶
3. Me2O-P2O5-H2O solubility phase diagrams and growth of MeH2PO4 single crystals (Me = Li, Na, K, Rb, Cs, NH4) [J] . Soboleva LV, Voloshin AE Crystallography reports . 2004,第4期

机译：Me2O-P2O5-H2O溶解度相图和MeH2PO4单晶的生长（Me = Li，Na，K，Rb，Cs，NH4）
4. 1H NMR study of proton dynamics in (NH4)1-xRbx3H(SO4)2(x=0.54) [C] . International conference on solid state ionics . 2008

机译：（NH4）1-XRBX 3H（SO4）2（SO4）2的质子动力学（SO4）2（x = 0.54），1h NMR研究
5. New phases in the hydrous ferric sulfate system, a supporting argument that the mineral lausenite is of formula Fe2(SO4 )3·5H2O and the crystal structure refinement and hydrogen bonding scheme of the minerals quenstedtite and romerite [D] . Westland, Robin Elizabeth 2012

机译：含水硫酸铁体系中的新相，支持的论据是，矿物绿铁矿的分子式为Fe2（SO4）3·5H2O，以及芒硝和硅镁矿矿物的晶体结构细化和氢键合方案
6. Systematic Improvement of Protein Crystals by Determining the Supersolubility Curves of Phase Diagrams [O] . Emmanuel Saridakis, Naomi E. Chayen 2003

机译：通过确定相图的超溶解度曲线来系统地改善蛋白质晶体
7. Influence of NH4-Rb substitution on the phase transitions with different kinds of proton disorder in mixed (NH4)1–xRbx3H(SO4)2crystals [O] . A. I. Baranov, V. V. Dolbinina, E. D. Yakushkin, 1998

机译：NH4-RB取代对混合（NH4）1-XRBX的不同质子障碍相变的影响（SO4）2译

Solubility phase diagrams of Me2SO4-NiSO4-H2O systems and the growth of Me2Ni(SO4)(2)center dot nH(2)O crystals [Me = Na, Rb, Cs; n=4, 6]

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