Structural study of [(CH3)(2)NH2](2)CoCl4 single crystals at room temperature

Pietraszko A; Kirpichnikova LF; Sheleg AU; Yachkovsky AY

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Structural study of [(CH3)(2)NH2](2)CoCl4 single crystals at room temperature

机译：室温下[（CH3）（2）NH2]（2）CoCl4单晶的结构研究

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The structure of the crystals grown from a solution of dimethylammonium and cobalt chlorides is determined. It is found that the crystals have the composition [(CH3)(2)NH2](2)CoCl4. At room temperature, the crystals are monoclinic (space group P2(1)/c, Z = 4) and the unit cell parameters are as follows: a = 8.545(2) angstrom, b = 11.447(2) angstrom, c = 13.313(3) angstrom, and beta = 90.10 degrees. Cations and anions form simple and bifurcated hydrogen bonds N-H center dot center dot center dot Cl.

机译：确定了由二甲基铵和氯化钴溶液生长的晶体的结构。发现该晶体具有组成[（CH3）（2）NH2]（2）CoCl4。在室温下，晶体是单斜晶体（空间群P2（1）/ c，Z = 4），晶胞参数如下：a = 8.545（2）埃，b = 11.447（2）埃，c = 13.313 （3）埃，贝塔= 90.10度。阳离子和阴离子形成简单且分叉的氢键N-H中心点中心点中心点Cl。

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《Crystallography reports》 |2006年第1期|共3页
作者
Pietraszko A; Kirpichnikova LF; Sheleg AU; Yachkovsky AY;
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正文语种 eng
中图分类晶体学;
关键词
FERROELECTRIC PHASE-TRANSITION; lt; NH2(CH3)2gt; 3SB2CL9;

机译：铁电相变;NH2（CH3）2 3SB2CL9;

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Structural study of [(CH3)(2)NH2](2)CoCl4 single crystals at room temperature

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