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首页> 外文期刊>Microporous and mesoporous materials: The offical journal of the International Zeolite Association >Thin film nanocomposite membranes filled with bentonite nanoparticles for brackish water desalination: A novel water uptake concept
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Thin film nanocomposite membranes filled with bentonite nanoparticles for brackish water desalination: A novel water uptake concept

机译:薄膜纳米复合膜填充有膨润土纳米颗粒,用于咸水脱盐:一种新的水吸收概念

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摘要

Bentonite nanoparticles (NPs) prepared via solvothermal method were filled into thin film nanocomposite (TFN) membranes for brackish water desalination. Membranes were prepared by the interfacial polymerization (IP) between m-phenylenediamine (MPD) aqueous solution and an organic solution of trimesoyl chloride (TMC); the IP reaction occurred on a support sheet of polysulfone (PSU). The NPs (<= 50 nm) were dispersed at different percentages, from 0 to 0.15%, in MPD solution during TFN membranes preparation. Scanning electron microscopy (SEM), surface area, pore size and zeta potential techniques were used to characterize the NPs. And SEM, transmission electron microscopy (TEM), attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR), contact angle measurement, and the membranes performance assessments were used for membrane characterization. Results showed that bentonite NPs improved the performance of all TFN membranes, as tested under the conditions of: 2000 ppm NaCl solution, 25 degrees C, and 300 psi (20.68 bar) trans-membrane pressure. With 0.1% NPs, the water flux was increased from 45.6 to 58.8 L/m(2) h in comparison with the control membrane and the salt rejection was simultaneously increased from 96.25 to 97.3%.
机译:通过溶剂质法制备的膨润土纳米颗粒(NPS)填充到薄膜纳米复合材料(TFN)膜中以进行咸水脱盐。通过M-苯二胺(MPD)水溶液与三咪酰氯(TMC)之间的有机溶液之间的界晶聚合(IP)制备膜; IP反应发生在聚砜(PSU)的支撑板上。在TFN膜制剂期间,在MPD溶液中以不同百分比分散在不同百分比的百分比,从0〜0.15%分散。扫描电子显微镜(SEM),表面积,孔径和Zeta潜在技术用于表征NPS。和SEM,透射电子显微镜(TEM),减弱的全反射傅里叶变换红外光谱(ATR FT-IR),接触角测量和膜性能评估用于膜表征。结果表明,膨润土NPS改善了所有TFN膜的性能,如在:2000ppm NaCl溶液,25℃和300psi(20.68巴)跨膜压力下所测试的。对于0.1%NPS,与对照膜相比,水通量从45.6升至58.8升/米(2)小时,并且盐排斥同时从96.25增加到97.3%。

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