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首页> 外文期刊>Crystallography reports >Refinement of the Crystal Structures of Biomimetic Weddellites Produced by Microscopic Fungus Aspergillus niger
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Refinement of the Crystal Structures of Biomimetic Weddellites Produced by Microscopic Fungus Aspergillus niger

机译:细微真菌黑曲霉产生的仿生线虫的晶体结构的细化

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摘要

The single-crystal structures of four biomimetic weddellites CaC_2O_4 ? (2 + x)H_2O with different contents of zeolitic water (x = 0.10–0.24 formula units) produced by the microscopic fungus Aspergillus niger were refined from X-ray diffraction data (R = 0.029–0.038). The effect of zeolitic water content on the structural stability of weddellite was analyzed. The parameter a was shown to increase with increasing x due to the increase in the distance between water molecules along this direction. The water content and structural parameters of the synthesized weddellites are similar to those of weddellites from biofilms and kidney stones.
机译:四种仿生方铅矿CaC_2O_4?的单晶结构从X射线衍射数据(R = 0.029–0.038)精制了由黑霉菌黑曲霉产生的具有不同含量的沸石水(x = 0.10–0.24公式单位)的(2 + x)H_2O。分析了沸石含水量对绿钨矿结构稳定性的影响。由于沿该方向的水分子之间距离的增加,表明参数a随着x的增加而增加。合成的辉绿岩的水含量和结构参数与生物膜和肾结石中的辉绿岩相似。

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