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Crystal growth and properties of Rb2Ni(SO4)(2) center dot 6H(2)O (RNSH)

机译:Rb2Ni(SO4)(2)中心点6H(2)O(RNSH)的晶体生长和性能

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摘要

Large single crystals of rubidium nickel hexahydrate Rb2Ni(SO4)(2) center dot 6H(2)O (RNSH) of optical quality were grown for the first time. The atomic structure of RNSH crystals was refined. A comparative analysis of the crystal structures of (M1+ )(2)Ni(SO4)(2) center dot 6H(2)O, where M1+ is K, Rb, or Cs, was performed. The solubility curve of RNSH in water was measured. The optical and thermogravimetric properties of RNSH were investigated. The internal defect structure of RNSH crystals was studied by X-ray topography.
机译:首次生长了具有光学质量的六水合nickel镍六水合物Rb2Ni(SO4)(2)中心点6H(2)O(RNSH)。 RNSH晶体的原子结构得到了改进。对(M1 +)(2)Ni(SO4)(2)中心点6H(2)O的晶体结构进行了比较分析,其中M1 +为K,Rb或Cs。测量了RNSH在水中的溶解度曲线。研究了RNSH的光学和热重性质。通过X射线形貌研究了RNSH晶体的内部缺陷结构。

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