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首页> 外文期刊>Crystallography reports >Synthesis, characterization, and properties of nanoscale titanium dioxide modifications with anatase and η-TiO_2 structures
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Synthesis, characterization, and properties of nanoscale titanium dioxide modifications with anatase and η-TiO_2 structures

机译:具有锐钛矿和η-TiO_2结构的纳米级二氧化钛修饰物的合成,表征和性质

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Nanoscale titanium dioxide modifications with anatase and η-TiO _2 structures have been obtained by the sulfate method. Bands characteristic of the η-TiO_2 phase are selected in the Raman and IR spectra of the samples containing this phase. A study of the properties of synthesized samples applying a complex of physicochemical methods revealed that nanocrystals in the samples containing phases of different modifications differ in size, structure, and surface composition. It is shown that the abovementioned nanoscale modifications are characterized by the efficient sorption of As (V), Bi (III), and V (V) from aqueous media; the degree of sorption depends on the size and structural form of nanocrystals.
机译:通过硫酸盐法获得了具有锐钛矿和η-TiO_2结构的纳米级二氧化钛修饰。在包含该相的样品的拉曼光谱和红外光谱中选择η-TiO_2相的特征带。使用多种物理化学方法对合成样品的性质进行的研究表明,样品中包含不同修饰相的纳米晶体在尺寸,结构和表面组成上均不同。结果表明,上述纳米级修饰的特征在于从水性介质中有效吸附As(V),Bi(III)和V(V)。吸附程度取决于纳米晶体的大小和结构形式。

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