Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review

Sergienko VS

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Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review

机译：VI族过渡金属过氧化合物的结构化学：II。钼和钨的过氧化物配合物：综述

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The specific features revealed in the structure of the molybdenum and tungsten peroxo complexes with the ratios M: O-2 = 1: 1, 1: 2, and 1: 4 are considered. It is demonstrated that the geometry of the coordination polyhedron of the metal atom is primarily determined by the "metal: peroxo ligand" ratio. Formally, the pentagonal bipyramidal coordination polyhedra of the Mo(VI) and W(VI) oxo monoperoxo and oxo diperoxo complexes (the coordination numbers of the metal atoms are equal to seven) have different geometries, namely, the MO(O-2)A(4) pseudooctahedral and MO(O-2)(2)A(2) pseudotrigonal bipyramidal configurations.

机译：考虑以M∶O-2 ＝ 1∶1、1∶2和1∶4的比例存在于钼和钨过氧配合物的结构中的特定特征。已证明金属原子配位多面体的几何形状主要由“金属：过氧配体”之比确定。形式上，Mo（VI）和W（VI）的oxo perperoxo和oxo diperoxo配合物（金属原子的配位数等于7）的五边形双锥体配位多面体具有不同的几何形状，即MO（O-2） A（4）伪八面体和MO（O-2）（2）A（2）伪三角双锥体构型。

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《Crystallography reports》 |2008年第1期|共29页
作者
Sergienko VS;
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正文语种 eng
中图分类晶体学;
关键词
X-RAY CRYSTAL; AMINO-ACID COMPLEXES; MOLECULAR-STRUCTURE; POTASSIUM OXODIPEROXOOXALATOMOLYBDATE(VI); CIS-TRIOXOTUNGSTEN(VI) COMPLEXES; COORDINATION-CHEMISTRY; SPECTROSCOPIC EVIDENCE; CATALYZED EPOXIDATION; DIPEROXO COMPOUND; PEROXOMOLYBDATES;

机译：X射线晶体;氨基酸络合物;分子结构;氧代过氧硫酸氧钾（VI）;CIS-三氧钨（VI）络合物;配位-化学;光谱证据;催化的环氧;过氧化物;

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1. Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review [J] . Sergienko VS Crystallography reports . 2008,第1期

机译：VI族过渡金属过氧化合物的结构化学：II。钼和钨的过氧化物配合物：综述
2. Experimental and Theoretical Electron Density Study of the Peroxo Function in Oxoperoxo(pyridine-2,6-dicarboxylato)(hexamethylphosphoramide)molybdenum(VI): Implications for Olefin Epoxidatin by Peroxo Transition Metal Complexes [J] . P. Macchi, A. J. Schultz, F. K. Larsen, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第40期

机译：过氧过氧（-2,6-吡啶二甲酸）（六甲基磷酰胺）钼（VI）中过氧官能度的实验和理论电子密度研究：过氧过渡金属配合物对烯烃环氧过氧化物的影响
3. THE VERSATILE CHEMISTRY OF PEROXO COMPLEXES OF VANADIUM, MOLYBDENUM AND TUNGSTEN AS OXIDANTS OF ORGANIC COMPOUNDS [J] . VALERIA CONTE, FULVIO DI FURIA, STEFANO MORO Journal of Physical Organic Chemistry . 1996,第6期

机译：钒，钼和钨的过氧化物络合物作为有机化合物的氧化剂的通用化学
4. A New Proton Conductive Membrane - Tungsten Peroxo Complex Doped Sol-Gel Organic/Inorganic Nanocomposite Polymer [C] . Hitoshi NAKAJIMA, Itaru HONMA Symposium on Proton Conducting Membrane Fuel Cells . 2005

机译：一种新的质子传导膜 - 钨过氧乙烯复合物掺杂溶胶 - 凝胶有机/无机纳米复合材料
5. Model complexes as probes of heme and nonheme enzymatic mechanisms: (1) Ferric peroxo porphyrin complexes as mimics of P450 enzymes using the ferric peroxo species as an active oxidant. (2) Strongly oxidizing iron (III) complexes as models of the active site intermediates of lipoxygenase. [D] . Wertz, Diana L. 1999

机译：将复合物建模为血红素和非血红素酶机制的探针：（1）使用过氧化铁物种作为活性氧化剂，将过氧化铁卟啉复合物模拟为P450酶。（2）强氧化铁（III）络合物作为脂氧合酶活性位点中间体的模型。
6. Bioinorganic Chemistry Special Feature: Superoxo μ-peroxo and μ-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: Copper ligand influences in cytochrome c oxidase models [O] . Eunsuk Kim, Matthew E. Helton, Ian M. Wasser, 2003

机译：生物无机化学的特殊功能：来自血红素/ O2和血红素-Cu / O2反应性的Superoxoμ-peroxo和μ-oxo络合物：铜配体对细胞色素c氧化酶模型的影响
7. Biomimetic hydroxylation catalysis with bis(pyrazolyl)methane copper peroxo complexes and structural studies on transition metal bis(pyrazolyl)methane complexes [O] . Wilfer Claudia 2015

机译：双（吡唑基）甲烷铜过氧配合物的仿生羟基化催化及过渡金属双（吡唑基）甲烷配合物的结构研究
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 62. Synthesis of Penta-, Hexa-, and Hepta-Heteronuclear Metal Cluster Compounds Involving Tungsten or Molybdenum with Platinum or Nickel [R] . Davies, S. J., Elliott, G. P., Howard, J. A., 1987

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。第62部分。涉及钨或钼与铂或镍的五 - ，六 - 和七 - 异 - 核金属簇化合物的合成

Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review

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