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Structural features of low-dimensional molecular conductors - Representatives of new hybrid polyfunctional materials: Review

机译：低维分子导体的结构特征-新型混合多功能材料的代表：综述

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摘要

The crystal structures of the family of low-dimensional molecular conductors based on radical cation salts of different organic pi donors with photochromic and magnetic metal complexes as anions have been considered. This class of supramolecular systems demonstrates a large variety of structural types and a wide range of transport properties. The specificity of the structure and properties of such hybrid materials is illustrated by several examples. The crystallochemical analysis of the conductors considered indicates the possibility of purposeful control of their transport properties via changing of the charge, sizes, shape, and symmetry of the anionic block components. The specificity of the crystal structure and properties of some organic conductors shows that such systems can be used as model systems in the study of new physical phenomena related to electron correlation and effects of charge ordering.
机译：已经考虑了基于不同有机pi供体的自由基阳离子盐，以光致变色和磁性金属配合物为阴离子的低维分子导体家族的晶体结构。这类超分子系统展示了多种结构类型和广泛的传输特性。这种杂化材料的结构和性质的特异性通过几个例子说明。对所考虑导体的结晶化学分析表明，通过改变阴离子嵌段组分的电荷，尺寸，形状和对称性，有目的地控制其传输性能是可能的。某些有机导体的晶体结构和特性的特异性表明，此类系统可以用作模型系统，用于研究与电子相关性和电荷有序效应有关的新物理现象。

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