Crystal structure of potassium titanyl phosphate doped with zirconium

Alekseeva OA; Dudka AP; Sorokina NI; Pietraszko A; Rabadanov MK; Agapova EI; Voronkova VI; Simonov VI

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Crystal structure of potassium titanyl phosphate doped with zirconium

机译：锆掺杂钛氧钛酸钾的晶体结构

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This paper reports on the results of precision X-ray structural investigations of single crystals of the compounds KTi0.96Zr0.04OPO4 (at 293 K) and KTi0.97Zr0.03OPO4 (at 293 and 105 K). No significant splitting of the positions occupied by potassium atoms is revealed. This result is in agreement with a considerable decrease in the electrical conductivity of potassium titanyl phosphate KTiOPO4 (KTP) crystals doped with zirconium (KTP : Zr) as compared to crystals of undoped potassium titanyl phosphate. It is established that the difference between the Ti-O bond lengths in chains formed by titanium octahedra is not a single structural parameter responsible for the nonlinear optical properties of crystals in this series.

机译：本文报道了化合物KTi0.96Zr0.04OPO4（在293 K）和KTi0.97Zr0.03OPO4（在293和105 K）的单晶的精确X射线结构研究结果。没有发现钾原子占据的位置有明显的分裂。该结果与掺杂有锆的磷酸钛氧基钾KTiOPO 4（KTP）晶体（KTP：Zr）的电导率相比未掺杂的磷酸钛氧基钾晶体的电导率显着降低是一致的。可以确定的是，八面体钛形成的链中Ti-O键长之间的差异不是导致该系列晶体非线性光学性质的单个结构参数。

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来源
《Crystallography reports》 |2007年第4期|共9页
作者
Alekseeva OA; Dudka AP; Sorokina NI; Pietraszko A; Rabadanov MK; Agapova EI; Voronkova VI; Simonov VI;
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正文语种 eng
中图分类晶体学;
关键词
NONLINEAR OPTICAL-PROPERTIES; SINGLE-CRYSTALS; KTIOPO4 CRYSTALS; REDUCED DATA; GROWTH; NB;

机译：非线性光学特性;单晶体;KTIOPO4晶体;数据减少;增长;NB;

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1. 具有高电荷分离效率和光催化活性的锆掺杂钛酸钙的制备 [J] . 黄晓俊, 严欣, 吴海燕, 中国有色金属学报（英文版） . 2016,第002期
2. 具有高电荷分离效率和光催化活性的锆掺杂钛酸钙的制备 [J] . 黄晓俊, 严欣, 吴海燕, 中国有色金属学报：英文版 . 2016,第002期
3. Crystal structure of potassium titanyl phosphate doped with zirconium [J] . Alekseeva OA, Dudka AP, Sorokina NI, Crystallography reports . 2007,第4期

机译：锆掺杂钛氧钛酸钾的晶体结构
4. Synthesis, properties, and structure of potassium titanyl phosphate single crystals doped with hafnium [J] . Orlova E.I., Kharitonova E.P., Novikova N.E., Crystallography reports . 2010,第3期

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5. Structure and properties of antimony-doped potassium titanyl phosphate single crystals [J] . Alekseeva OA, Krotova OD, Sorokina NI, Crystallography reports . 2005,第4期

机译：锑掺杂钛氧钛酸钾单晶的结构与性能
6. Pyroelectricity and its role in optical damage of potassium titanyl phosphate crystals [C] . Author(s): D.W. Cooke Los Alamos National Lab. Los Alamos NM USA, B.L. Bennett Los Alamos National Lab. Los Alamos NM USA, Ross E. Muenchausen Los Alamos National Lab. Los Alamos NM USA, Laser-Induced Damage in Optical Materials: 1996 . 1997

机译：钛氧钛磷酸钾晶体的热电及其在光学损伤中的作用
7. Flux growth, characterization, and structure-property relations for inorganic oxide crystals: Lithium triborate, potassium titanyl phosphate and lead titanate. [D] . Huang, Yutung. 1993

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8. Evaluation of temperature rises during the application of different power levels of potassium titanyl phosphate and neodymium-doped:yttrium aluminum garnet lasers to external primary root canals [O] . Recai Zan, Ihsan Hubbezoglu, Murat Unal 2016

机译：对不同功率水平的磷酸钛氧钾和掺钕钇铝石榴石激光器施加不同功率水平的温度评估
9. Review on Gray Track Effects on Potassium Titanyl Phosphate Single Crystals [O] . Narayana Perumal R 2017

机译：磷酸钛磷酸钾单晶灰度效应综述

Crystal structure of potassium titanyl phosphate doped with zirconium

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