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首页> 外文期刊>Crystallography reports >The absorption and circular dichroism spectra of langasite family crystals doped with chromium ions
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The absorption and circular dichroism spectra of langasite family crystals doped with chromium ions

机译:铬离子掺杂的硅酸钾族晶体的吸收和圆二色光谱。

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摘要

The absorption and circular dichroism spectra of langasite family crystals, La3Ga5SiO14, La3Ga5GeO14, Ca3Ga2Ge4O14, Sr3Ga2Ge4O14 (red), Sr3Ga2Ge4O14 (green), La3Ta0.5Ga5.5O14, and La3Nb0.5Ga5.5O14, which were doped with chromium ions, have been investigated in the range of 240-850 nm. It is shown that chromium ions are incorporated into the structure of the investigated crystals both in the octahedrally (Cr3+ ion in 1a octahedron) and tetrahedrally (Cr4+ ion in 2d tetrahedron) coordinated positions. The ion ratio Cr3+/Cr4+ changes in a wide range in the crystals studied.
机译:掺杂了铬离子的镧铁矿族晶体La3Ga5SiO14,La3Ga5GeO14,Ca3Ga2Ge4O14,Sr3Ga2Ge4O14(红色),Sr3Ga2Ge4O14(绿色),La3Ta0.5Ga5.5O14和La3Nb0.5Ga5.5O14的吸收光谱和圆二色谱在240-850 nm范围内结果表明,铬离子在八面体(1a八面体中的Cr3 +离子)和四面体(2d四面体中的Cr4 +离子)配位位置都掺入了所研究晶体的结构中。离子比Cr3 + / Cr4 +在所研究的晶体中变化很大。

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