Investigation of structural transformations in pyridine nitrate at low temperatures and high pressures

Kozlenko DP; Wasicki JW; Glazkov VP; Kichanov SE; Nawrocik W; Savenko BN

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Investigation of structural transformations in pyridine nitrate at low temperatures and high pressures

机译：低温高压下硝酸吡啶的结构转变研究

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The structural transformations in pyridine nitrate PyHNO3 (C5D5NHNO3) are investigated by neutron diffraction in the temperature range 16-300 K at normal pressure and in the high-pressure range 0-3.5 GPa at room temperature. A new high-pressure phase with a monoclinic structure (space group P2(1)/c) is revealed in the PyHNO3 compound at pressures P > P-tr similar to I GPa. The geometry of hydrogen bonds and the coordination of the PyH+ and NO3- ions in the structure of the PyHNO3 compound are studied as a function of the temperature and pressure. (C) 2005 Pleiades Publishing, Inc.

机译：硝酸吡啶吡啶PyHNO3（C5D5NHNO3）的结构转变通过中子衍射在常压下16-300 K的温度范围内和在室温下0-3.5 GPa的高压范围内进行研究。在PyHNO3化合物中，类似于I GPa的压力P> P-tr，发现了具有单斜晶结构的新高压相（空间群P2（1）/ c）。研究了PyHNO3化合物结构中氢键的几何形状以及PyH +和NO3-离子的配位与温度和压力的关系。（C）2005年Pleiades Publishing，Inc.

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《Crystallography reports》 |2005年第1期|共7页
作者
Kozlenko DP; Wasicki JW; Glazkov VP; Kichanov SE; Nawrocik W; Savenko BN;
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正文语种 eng
中图分类晶体学;
关键词
NEUTRON-DIFFRACTION; FERROELECTRIC PROPERTIES; TETRAFLUOROBORATE; CRYSTAL;

机译：中子衍射;铁电性能;四氟硼酸盐;晶体;

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1. Investigation of structural transformations in pyridine nitrate at low temperatures and high pressures [J] . Kozlenko DP, Wasicki JW, Glazkov VP, Crystallography reports . 2005,第1期

机译：低温高压下硝酸吡啶的结构转变研究
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Investigation of structural transformations in pyridine nitrate at low temperatures and high pressures

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