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首页> 外文期刊>Crystallography reports >Supramolecular Organization of the Crystal Structure of cis-Bis(thiosemicarbazide)palladium(II) ortho-Hydrophthalate
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Supramolecular Organization of the Crystal Structure of cis-Bis(thiosemicarbazide)palladium(II) ortho-Hydrophthalate

机译:顺式双(硫代氨基脲)钯(II)邻苯二甲酸氢盐的晶体结构的超分子组织

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This paper reports on the synthesis of a new palladium(II) thiosemicarbazide complex of the composition [Pd(HL)(2)](HPht)(2) center dot 4H(2)O(I) (where HL is N(1)H2-N(2)H-C(3)(=S)-N(4)H-2 and HPht(-) is a monoanion of ortho-phthalic acid) and the results of an investigation of its structure. It has been demonstrated that two organic ligands are bidentately coordinated in the neutral form through a set of N and S donor atoms, which are located in the cis position with respect to the central metal atom. Three independent water molecules are joined by hydrogen bonds into the centrosymmetric associate {H2O}(6). In the crystal, thiosemicarbazide cationic complexes of palladium(II), monophthalate anions, and water molecules are self-organized into a supramolecular system with the formation of a three-dimensional structure based on ionic and hydrogen bonds.
机译:本文报道了一种新的合成的钯(II)硫代氨基脲复合物,其组成为[Pd(HL)(2)](HPht)(2)中心点4H(2)O(I)(其中HL为N(1 )H2-N(2)HC(3)(= S)-N(4)H-2和HPht(-)是邻苯二甲酸的单阴离子),并对其结构进行了研究。已经证明,两个有机配体通过一组N和S供体原子以中性形式双齿配位,该N和S供体原子相对于中心金属原子位于顺式位置。三个独立的水分子通过氢键连接到中心对称缔合物{H2O}(6)中。在晶体中,钯(II),单邻苯二甲酸酯阴离子和水分子的硫代氨基脲阳离子复合物自组织为超分子系统,并基于离子和氢键形成三维结构。

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