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Tubular chains in the structures of natural and synthetic silicates

机译:天然和合成硅酸盐结构中的管状链

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Tubular chains in the structures of natural and synthetic silicates have been described and systematized using the theory of graphs and by unfolding the tube topology onto a plane. Eight types of tubular chains have been considered: seven silicon-oxygen chains and one mixed titanosilicate chain; their topological and geometric characteristics are analyzed. It is shown that the presence of large cavities in tubes is generally related to their occupation by large low-valence cations (K ~+, Cs ~+, Ba ~(2+), Sr ~(2+), etc.) and water molecules. The overwhelming majority of minerals containing tubular silicate fragments were found in hydrothermal veins of alkaline massifs in Russia and abroad.
机译:天然和合成硅酸盐结构中的管状链已通过图论并通过将管形拓扑展开到一个平面上进行了描述和系统化。已经考虑了八种类型的管状链:七个硅-氧链和一个混合的钛硅酸盐链;分析了它们的拓扑和几何特征。结果表明,试管中大孔的存在通常与大低价阳离子(K〜+,Cs〜+,Ba〜(2 +),Sr〜(2+)等)的占据有关,并且水分子。在俄罗斯和国外,绝大多数碱性管状物的热液脉中都发现了含有管状硅酸盐碎片的矿物。

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