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首页> 外文期刊>Crystallography reports >Synthesis and crystal structure of 3-ammoniumphenyl sulfone selenate, 3-aminophenyl sulfone [C_(12)H_(14)N_2O _2S]SeO_4 · [C_(12)H_(12)N _2O_2S]
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Synthesis and crystal structure of 3-ammoniumphenyl sulfone selenate, 3-aminophenyl sulfone [C_(12)H_(14)N_2O _2S]SeO_4 · [C_(12)H_(12)N _2O_2S]

机译:3-铵苯基砜硒酸酯,3-氨基苯基砜[C_(12)H_(14)N_2O _2S] SeO_4·[C_(12)H_(12)N _2O_2S]的合成及晶体结构

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摘要

The crystal structure of [C_(12)H_(14)N_2O _2S]SeO_4 · [C_(12)H_(12)N _2O_2S] was determined by X-ray diffraction on single crystal. Crystals are orthorhombic, space group Pbca, with cell parameters a = 11.545 (1), b = 8.143 (1), c = 55.783(1)?, V = 5244.2 (8) ?~3 and Z = 8. The structure can be described as organic layers built by [C_(12)H_(14)N_2O_2S]~(2+) cations and [C_(12)H_(12)N_2O_2S] molecules, parallel to ab plane, between which the inorganic groups SeO _4 ~(2-) are inserted. In this atomic arrangement, H-bonds between the different species play an important role in the three-dimensional network cohesion.
机译:通过单晶的X射线衍射确定[C_(12)H_(14)N_2O _2S] SeO_4·[C_(12)H_(12)N _2O_2S]的晶体结构。晶体是正交晶体,空间群为Pbca,晶胞参数为a = 11.545(1),b = 8.143(1),c = 55.783(1)?、 V = 5244.2(8)?〜3和Z = 8。可以说是由[C_(12)H_(14)N_2O_2S]〜(2+)阳离子和[C_(12)H_(12)N_2O_2S]分子平行于ab平面构建的有机层,其间的无机基团SeO _4插入〜(2-)。在这种原子排列中,不同物种之间的氢键在三维网络凝聚中起着重要作用。

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