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Conductivity limit of fluorine-conducting solid electrolytes for electrochemical devices operating at room temperature

机译:室温下运行的电化学装置用含氟固体电解质的电导率极限

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摘要

An analysis of the characteristics of operating devices and prototypes based on fluorine-conducting solid electrolytes allows for estimating the lower fluoride conductivity limits sigma(293 K) that are sufficient for using these electrolytes in electrochemical devices operating at room temperature. The estimated sigma(293 K) values for different electrochemical devices differ strongly: sigma(293 K) > 10(-3) S/cm for fluorine ion current sources and fluorine gas detection sensors and sigma(293 K) > 10(-5) S/cm for fluorine fluid sensors (ion-selective electrodes). The fluoride materials that are promising as solid electrolytes in fluorine-ion batteries and accumulators, fluorine-selective electrodes, and gas fluorine gas sensors operating at room temperature are listed.
机译:对基于氟导电固体电解质的操作装置和原型的特性进行分析,可以估算出较低的氟化物电导率限值sigma(293 K),这足以在室温下运行的电化学装置中使用这些电解质。不同电化学装置的估计sigma(293 K)值差异很大:对于氟离子电流源和氟气检测传感器,sigma(293 K)> 10(-3)S / cm,而sigma(293 K)> 10(-5) )S / cm,用于氟流体传感器(离子选择电极)。列出了有望在氟离子电池和蓄电池,氟选择电极和在室温下工作的气体氟气传感器中用作固体电解质的氟化物材料。

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