X-Ray Diffraction Analysis of LiCu2O2 Crystals with Additives of Silver Atoms

Sirotinkin V. P.; Bush A. A.; Kamentsev K. E.; Dau H. S.; Yakovlev K. A.; Tishchenko E. A.

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X-Ray Diffraction Analysis of LiCu2O2 Crystals with Additives of Silver Atoms

机译：含银原子添加剂的LiCu2O2晶体的X射线衍射分析

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Silver-containing LiCu2O2 crystals up to 4 x 8 x 8 mm in size were grown by the crystallization of 80(1-x)CuO center dot 20(x)AgNO(3) center dot 20Li(2)CO(3) (0 <= x <= 0.5) mixture melt. According to the X-ray spectral and Rietveld X-ray diffraction data, the maximum amount of silver incorporated in the LiCu2O2 structure is about 4 at % relative to the copper content. It was established that silver atoms occupy statistically crystallographic positions of lithium atoms. The incorporation of silver atoms is accompanied by a noticeable increase in parameter N of the LiCu2O2 rhombic unit cell, a slight increase in parameter a, and a slight decrease in parameter b.

机译：通过80（1-x）CuO中心点20（x）AgNO（3）中心点20Li（2）CO（3）（0的结晶）可以生长尺寸最大为4 x 8 x 8 mm的含银LiCu2O2晶体<= x <= 0.5）混合物熔体。根据X射线光谱和Rietveld X射线衍射数据，掺入LiCu 2 O 2结构中的银的最大量相对于铜含量为约4at％。已经确定银原子占据锂原子的统计晶体位置。银原子的掺入伴随着LiCu 2 O 2菱形晶胞的参数N的显着增加，参数a的略微增加和参数b的略微下降。

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《Crystallography reports》 |2015年第5期|共5页
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Sirotinkin V. P.; Bush A. A.; Kamentsev K. E.; Dau H. S.; Yakovlev K. A.; Tishchenko E. A.;
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1. X-Ray Diffraction Analysis of LiCu2O2 Crystals with Additives of Silver Atoms [J] . Sirotinkin V. P., Bush A. A., Kamentsev K. E., Crystallography reports . 2015,第5期

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X-Ray Diffraction Analysis of LiCu2O2 Crystals with Additives of Silver Atoms

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