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Catalytic Activity of Iron Hydroxides and Manganese Hydroxides in the Deoxygenation of Water

机译：催化活性铁氢氧化铁和锰氢氧化物在水中的脱氧中

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摘要

Catalysts prepared by the modification of FIBAN K-4 and FIBAN X-1 fibrous ion exchangers with the hydroxides of iron and manganese were developed and tested in a water deoxygenation process. It was established that the samples obtained by the supporting of Fe(III) hydroxide onto the FIBAN X-1 ampholyte were most effective. The conclusion that the high activity of the catalytic system is caused by the formation of a mixed phase of Fe(II) and Fe( III) hydroxides of the spinel type containing mobile ( weakly bound) lattice oxygen was made. A reaction scheme was proposed to explain the reaction mechanism.
机译：通过在水脱氧过程中改变具有铁和锰的氢氧化物的纤维K-4和纤维X-1纤维离子交换剂制备的催化剂。 建立通过将Fe（III）氢氧化物支撑到氮氧化物X-1两晶水解上获得的样品最有效。 结论是，催化体系的高活性是由形成含有流动（弱束缚）晶格氧的尖晶石型Fe（II）和Fe（III）和Fe（III）氢氧化物的混合相引起的。 提出了反应方案来解释反应机制。

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