Ring-Opening Metathesis Polymerization (ROMP) of Fullerene-Containing Monomers in the Presence of a First-Generation Grubbs Catalyst

Biglova Yu. N.; Mustafin A. G.; Torosyan S. A.; Biglova R. Z.; Miftakhov M. S.

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Ring-Opening Metathesis Polymerization (ROMP) of Fullerene-Containing Monomers in the Presence of a First-Generation Grubbs Catalyst

机译：在第一代GRUBBS催化剂存在下，含富勒烯的单体的开环复分解聚合（ROMP）

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摘要

New norbornene-type monomers containing covalently bound C60 fullerene have been obtained. In the presence of the 1st generation Grubbs catalyst [(PCy3)(2)Cl2RuCHPh] (Cy is cyclohexyl), these monomers smoothly undergo homopolymerization and copolymerization with parent fullerene-free monomers. The homopolymers are insoluble in common organic solvents, while the copolymers obtained at different molar ratios to their fullerene-free analogues are very soluble in organic solvents and can be suitable for the preparation of thin films.

机译：已经获得了含有共价结合的C60富勒烯的新的降冰片烯类单体。在第1代GRUBBS催化剂[（PCY3）（2）CL2RUCHPH]（C CI是环己基）的情况下，这些单体平滑地经历均聚物和共聚与母体富勒烯单体。均聚物在普通的有机溶剂中不溶，而在不同摩尔比在其富勒烯的类似物中获得的共聚物非常易溶于有机溶剂，并且可以适用于制备薄膜。

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来源
《Kinetics and catalysis》 |2017年第2期|共11页
作者
Biglova Yu. N.; Mustafin A. G.; Torosyan S. A.; Biglova R. Z.; Miftakhov M. S.;
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作者单位

Bashkir State Univ Ufa 450076 Bashkortostan Russia;

Bashkir State Univ Ufa 450076 Bashkortostan Russia;

Russian Acad Sci Ufa Inst Chemfirstry Ufa 450054 Bashkortostan Russia;

Bashkir State Univ Ufa 450076 Bashkortostan Russia;

Russian Acad Sci Ufa Inst Chemfirstry Ufa 450054 Bashkortostan Russia;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
metathesis polymerization; Grubbs catalyst; fullerene-containing monomers and polymers;

机译：复分解聚合;GRUBBS催化剂;含富勒烯的单体和聚合物;

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专利

1. Ring-Opening Metathesis Polymerization (ROMP) of Fullerene-Containing Monomers in the Presence of a First-Generation Grubbs Catalyst [J] . Biglova Yu. N., Mustafin A. G., Torosyan S. A., Kinetics and catalysis . 2017,第2期

机译：在第一代GRUBBS催化剂存在下，含富勒烯的单体的开环复分解聚合（ROMP）
2. Synthesis of Multiple Hydrogen-Bonded Unit Containing Polymer via Acyclic Diene Metathesis (ADMET) Polymerization of Oligoamide Monomer with Grubbs-Type Olefin Metathesis Catalysts [J] . K. Luo, X.S. Pan, Y.A. Yang Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2014,第23期

机译：格鲁布斯型烯烃复分解催化剂通过低聚酰胺单体的无环二烯复分解（ADMET）聚合合成含氢键合单元的聚合物
3. Improved Molecular Weight Control in Ring-Opening Metathesis Polymerization (ROMP) Reactions with Ru-Based Olefin Metathesis Catalysts Using N Donors and Acid: A Kinetic and Mechanistic Investigation [J] . Dunbar MA, Balof SL, LaBeaud LJ, Chemistry: A European journal . 2009,第45期

机译：氮原子和酸与钌基烯烃复分解催化剂在开环复分解聚合（ROMP）反应中改进的分子量控制：动力学和机理研究
4. Synthesis of End Ailylphenol Functionalized Polymers via Ring-Opening Metathesis Polymerization (ROMP): Novel Polymeric Phenolic Stabilizers [C] . Boyong Xue, Akinori Toyota 5th International Symposium on High-Tech Polymer Materials（HTPM-V）（第五届国际高技术高分子材料学术会议）论文集 . 2008

机译：经由开环复分解聚合（ROMP）合成的末端烷基苯酚官能化的聚合物：新型高分子酚稳定剂
5. Functionalized polymers from ring-opening metathesis polymerization through monomer design [D] . Walker, Ron. 2009

机译：通过单体设计来自开环复分解聚合的官能化聚合物
6. αω-Epoxide Oxetane and Dithiocarbonate Telechelic Copolyolefins: Access by Ring-Opening Metathesis/Cross-Metathesis Polymerization (ROMP/CM) of Cycloolefins in the Presence of Functional Symmetric Chain-Transfer Agents [O] . Elise Vanbiervliet, Stéphane Fouquay, Guillaume Michaud, 2018

机译：αω-环氧氧杂环丁烷和二硫代碳酸酯远螯共聚烯烃：在功能对称链转移剂存在下通过环烯烃的开环复分解/交叉复分解聚合（ROMP / CM）访问
7. Remote Control Grubbs Catalysts That Modulate Ring-Opening Metathesis Polymerizations [O] . Teator, Aaron J., Bielawski, Christopher W. 2017

机译：远程控制格鲁布斯催化剂，调节开环复分解聚合

Ring-Opening Metathesis Polymerization (ROMP) of Fullerene-Containing Monomers in the Presence of a First-Generation Grubbs Catalyst

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