Large-scale printing synthesis of transition metal phosphides encapsulated in N, P co-doped carbon as highly efficient hydrogen evolution cathodes

Xiao Jian; Zhang Zheye; Zhang Yan; Lv Qiying; Jing Feng; Chi Kai; Wang Shuai

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Large-scale printing synthesis of transition metal phosphides encapsulated in N, P co-doped carbon as highly efficient hydrogen evolution cathodes

机译：大规模印刷合成在N，P掺杂碳中包封的过渡金属磷酸作为高效氢化阴极

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The large-scale synthesis accompanying structural modulation of efficient noble-metal-free catalysts with facile kinetics for the hydrogen evolution reaction (HER) is still a big challenge for electrolytic water splitting. Herein, we report a simple inkjet printing technology for the large-scale synthesis of a series of transition metal phosphide (TMP) nanoparticles encapsulated in N, P co-doped carbon supported on carbon fiber cloth (CF@NPC-TMP, TM = Mo, Co, Ni, Fe) as highly efficient hydrogen evolution cathodes using ionic liquids as phosphorus and carbon sources. The in-situ carbon nanolayers derived from ionic liquids not only expose abundant catalytically active sites and allow rapid electron transport to the catalytically active sites during HER but also effectively prevent the TMP nanoparticles from corroding to enhance their stability. All the as-prepared CF@NPC-TMP electrodes show ideal electrocatalytic performance for HER. Especially, the CF@NPC-MoP electrode only requires overpotentials of 87 and 145 mV to drive cathodic current densities of 10 and 100 mA cm(-2) in 0.5M H2SO4, respectively. In addition, this electrode continuously operates at a constant current density of 10 mA cm(-2) for 20 h with negligible rise in operating potential. The resultant CF@NPC-TMP electrodes also show ideal electrocatalytic activities toward HER in alkaline and neutral media. Hence, the synthesis strategy developed in this study may spark interest in research on TMP-based nanomaterials for various applications.

机译：伴随高贵金属 - 无金属催化剂的结构调节的大规模合成，用于氢进化反应（她）仍然是电解水分裂的巨大挑战。在此，我们报告了一种简单的喷墨印刷技术，用于大规模合成的一系列过渡金属磷化物（TMP）纳米颗粒包封在碳纤维布（CF @ NPC-TMP，TM = Mo）上封装在N，P共掺杂碳中，Co，Ni，Fe）作为使用离子液体作为磷和碳源的高效氢化阴极。衍生自离子液体的原位碳纳米黑子不仅暴露丰富的催化活性位点，并且在其期间允许快速电子传输到催化活性位点，但也有效地防止TMP纳米颗粒腐蚀以增强它们的稳定性。所有的AS准备的CF @ NPC-TMP电极为她表示理想的电催化性能。特别地，CF @ NPC-MOP电极仅需要87和145mV的过电位，以分别在0.5M H 2 SO 4中驱动10和100 mA（-2）的阴极电流密度。另外，该电极以10mA cm（-2）的恒定电流密度连续地操作20小时，运行电位的上升可忽略不计。所得CF @ NPC-TMP电极还显示出碱性和中性介质的理想电催化活性。因此，本研究中开发的合成策略可能会引发对各种应用的基于TMP的纳米材料的研究兴趣。

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来源
《Nano Energy》 |2018年第2018期|共8页
作者
Xiao Jian; Zhang Zheye; Zhang Yan; Lv Qiying; Jing Feng; Chi Kai; Wang Shuai;
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作者单位

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

Huazhong Univ Sci &

Technol State Key Lab Digital Mfg Equipment &

Technol Key Lab Mat Chem Energy Convers &

Storage Minist Educ Sch Chem &

Chem Engn Wuhan 430074 Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类能源与动力工程;
关键词
Electrocatalysis; Hydrogen evolution reaction; Transition metal phosphide; Ionic liquid; N; P co-doped carbon; Inkjet printing;

机译：电殖分析;氢气进化反应;过渡金属磷化物;离子液体;n;p共掺杂碳;喷墨印刷;

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专利

1. Large-scale printing synthesis of transition metal phosphides encapsulated in N, P co-doped carbon as highly efficient hydrogen evolution cathodes [J] . Xiao Jian, Zhang Zheye, Zhang Yan, Nano Energy . 2018,第期

机译：大规模印刷合成在N，P掺杂碳中包封的过渡金属磷酸作为高效氢化阴极
2. Rational Synthesis of Metal-Organic Framework-Derived Noble Metal-Free Nickel Phosphide Nanoparticles as a Highly Efficient Cocatalyst for Photocatalytic Hydrogen Evolution [J] . D. Praveen Kumar, Jiha Choi, Sangyeob Hong ACS Sustainable Chemistry & Engineering . 2016,第12期

机译：合理合成金属-有机骨架衍生的无贵金属的磷酸镍纳米粒子，作为光催化制氢的高效助催化剂
3. Highly efficient hydrogen evolution from water electrolysis using nanocrystalline transition metal phosphide catalysts [J] . Wu Weiming, Wu Xiao-Yuan, Wang Sa-Sa, RSC Advances . 2018,第69期

机译：利用纳米晶过渡金属磷化物催化剂从水电解高效氢化
4. (Invited) Boron and Nitrogen Co-Doped Porous Carbon Nanofibers As Metal-Free Electrocatalysts for Highly Efficient Ammonia Electrosynthesis [C] . Yang Hou, Yan Kong Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：（邀请）硼和氮掺杂多孔碳纳米纤维作为无金属电催化剂，用于高效氨电催化剂
5. Highly enantioselective transition metal-catalyzed hydrogenation reactions: An efficient tool for the synthesis of pharmaceuticals and other bioactive molecules. [D] . Sun, Xianfeng. 2008

机译：高度对映选择性的过渡金属催化的氢化反应：一种用于合成药物和其他生物活性分子的有效工具。
6. Highly Efficient Synthesis of Carbon-Based Molybdenum Phosphide Nanoparticles for Electrocatalytic Hydrogen Evolution [O] . Yang Li, Lun Cai, Qilin Huang, 2020

机译：高效合成碳基磷化钼纳米粒子用于电催化制氢
7. Highly efficient hydrogen evolution from water electrolysis using nanocrystalline transition metal phosphide catalysts [O] . Weiming Wu, Xiao-Yuan Wu, Sa-Sa Wang, 2018

机译：利用纳米晶过渡金属磷化物催化剂从水电解高效氢化

Large-scale printing synthesis of transition metal phosphides encapsulated in N, P co-doped carbon as highly efficient hydrogen evolution cathodes

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