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首页> 外文期刊>Laser physics letters >Spectroscopic properties of Er3+/Yb3+/Ho3+:CaLaGa3O7 and Er3+/Yb3+/Eu3+:CaLaGa3O7 crystals used in mid-infrared lasers
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Spectroscopic properties of Er3+/Yb3+/Ho3+:CaLaGa3O7 and Er3+/Yb3+/Eu3+:CaLaGa3O7 crystals used in mid-infrared lasers

机译:ER3 + / YB3 + / HO3 +:Calaga3O7和ER3 + / Yb3 + / Eu3 +:Calaga3O7在中红外激光器中使用的Calaga3O7晶体

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摘要

Er3+/Yb3+/Ho3+:CaLaGa3O7 (abbreviated as Er/Yb/Ho:CLGO) and Er3+/Yb3+/Eu3+:CaLaGa3O7 (Er/Yb/Eu: CLGO) crystals were grown by Czochralski technology and detailed spectroscopic analyses were carried out. The effects of Ho3+ and Eu3+ on the spectroscopic properties and mutual energy transfer mechanisms were investigated. It is found that the introductions of Ho3+ and Eu3+ are helpful in achieving enhanced mid-infrared (MIR) emission, as well as reduced near-infrared emission. Furthermore, the introduction of Ho3+ and Eu3+ depopulated the lower laser level through energy transfer and thus reduced the fluorescence lifetime of Er3+:4I13/2 in Er/Yb/Ho:CLGO and Er/Yb/Eu:CLGO crystals without significantly affecting the fluorescence lifetime of the upper laser level Er3+:4I11/2, which reduces the self-saturation problem to a degree. As a result, Eu3+ is a more appropriate deactivated ion than Ho3+ for Er3+ in this crystal. So Er/Yb/Eu:CLGO crystal could be a potential MIR gain medium for an enhanced 2.7 mu m laser.
机译:ER3 + / YB3 + / HO3 +:Calaga3O7(缩写为ER / YB / HO:CON)和ER3 + / YB3 + / EU3 +:Calaga3O7(ER / YB / EU:COM)晶体由Czochralski技术生长,进行详细的光谱分析。研究了HO3 +和EU3 +对光谱性能和相互能量转移机制的影响。发现HO3 +和EU3 +的介绍有助于实现增强的中红外(MIR)排放,以及减少近红外发射。此外,通过能量转移引入HO3 +和EU3 + Depopulated较低的激光水平,从而降低了ER3 +:4I13 / 2的荧光寿命:CON和ER / YB / EU:CLGO晶体而不会显着影响荧光上部激光器级ER3 +:4i11 / 2的寿命将自饱和问题降至一定程度。结果,EU3 +在该晶晶中比HO3 +更合适的去激活离子。所以ER / YB / EU:CLGO晶体可能是增强的2.7 mu M激光器的潜在miR增益培养基。

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