Mineralogy and Geochemistry of Pyrite and Arsenopyrite from the Zaozigou Gold Deposit in West Qinling Orogenic Belt, Central China: Implications for Ore Genesis

Tang Qingyan; Di Pengfei; Yu Man; Bao Jian; Zhao Ying; Liu Dongxiao; Wang Yuxi

摘要

Abstract > The Zaozigou gold deposit lies in the West Qinling orogenic belt, Gansu Province, China. It is one of the largest gold deposits, and the orebodies are hosted in fine‐grained slates intercalated with limestone of the Middle‐Triassic Gulangdi Formation and varied dykes. The gold orebodies are strictly controlled by the NE‐, NW‐, and SN‐trending tensional and shearing faults with high dipping angle. The mineralogy and geochemistry of pyrite and arsenopyrite are measured by electron microprobe. Pyrite has up to 0.12?wt.% Au, and arsenopyrite contains up to 0.17?wt.% Au. The antithetic correlation between S and As indicates the substitution of As for S in pyrite, and arsenic occurs in anionic As 1? state in the pyrite structure under the reduced conditions. Pyrite has relatively high Co (~364–2248?ppm) but relatively low Ni (~109–497?ppm) contents, with Co/Ni ratios ranging from ~1.63 to 10.50, indicating that the deposit originated from a volcanogenic fluid and remobilized by hydrothermal fluid. Au in arsenopyrite occurs as cationic Au in solid solution, whereas Au in pyrite is in solid solution and metal nanoparticles (Au 0 ). The texture characteristics and trace element geochemistry among cores, transition zones, and rims of pyrites demonstrate that there are at least four pulses of fluid participating in the generation of pyrite in the deposit. The calculated formation temperatures of the Zaozigou deposit vary from 148°C to 304°C, with an average temperature of 213°C based on Au contents in pyrite. The Pb isotopic compositions of pyrite samples suggest that the metallogenic materials of the Zaozigou deposit were derived from the mantle and upper crust. All the characteristics above lead us to draw the conclusion that the Zaozigou gold deposit is classified as an epithermal deposit. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > Zaozigou金矿床位于中国甘肃省的秦岭造山带。它是最大的金沉积物之一，矿体载于嵌入与中间三叠纪古兰迪形成和多种染料的石灰石的细粒状岩石。金矿石受到高浸渍角度的NE-，NW-和SN趋势的紧张和剪切故障。通过电子微探针测量吡啶矿石和亚苯甲酸盐的矿物学和地球化学。黄铁矿高达0.12？重量，Au，砷吡啶醇含量高达0.17μl.％au。 S与如硫铁矿中的依次的依次替代为抗静质相关性，并且砷在阴离子中发生 1？</ sup> 降低条件下的黄铁矿结构中的状态。硫铁矿具有相对高的CO（〜364-2248〜ppm），但相对较低的Ni（〜109-497〜ppm）内容物，Co / Ni比率范围为约1.63至10.50，表明沉积物源于火山液并重新染色通过水热流体。 Au在亚苯甲酸盐中作为固体溶液中的阳离子Au发生，而在黄铁矿中的Au是固溶体和金属纳米颗粒（Au 0 </ sup> ）。岩石，过渡区和刮板边缘之间的纹理特征和痕量元素地球化学表明，在沉积物中存在至少四种流体脉冲矿床。 Zaozigou沉积物的计算形成温度从148℃至304℃变化，基于黄铁矿中的Au含量为213℃的平均温度。黄铁矿样品的PB同位素组合物表明，枣嘴源沉积物的成矿材料源自披风和上地壳。以上所有特征都引导我们得出结论，即枣嘴沟金矿床被归类为岩石矿床。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-26853/'>《Resource Geology》</a> <b style="margin: 0 2px;">|</b><span>2019年第3期</span><b style="margin: 0 2px;">|</b><span>共19页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tang Qingyan&option=202" target="_blank" rel="nofollow">Tang Qingyan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Di Pengfei&option=202" target="_blank" rel="nofollow">Di Pengfei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Man&option=202" target="_blank" rel="nofollow">Yu Man;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bao Jian&option=202" target="_blank" rel="nofollow">Bao Jian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Ying&option=202" target="_blank" rel="nofollow">Zhao Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Dongxiao&option=202" target="_blank" rel="nofollow">Liu Dongxiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yuxi&option=202" target="_blank" rel="nofollow">Wang Yuxi;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Earth Sciences and Key Laboratory of Mineral Resources in Western China (Gansu Province)Lanzhou UniversityLanzhou China;</p> <p>Gansu Assessment Center of Mineral Resources ReservesLanzhou China;</p> <p>Gansu Institute of Land Resources Planning and ResearchLanzhou China;</p> <p>School of Earth Sciences and Key Laboratory of Mineral Resources in Western China (Gansu Province)Lanzhou UniversityLanzhou China;</p> <p>School of Earth Sciences and Key Laboratory of Mineral Resources in Western China (Gansu Province)Lanzhou UniversityLanzhou China;</p> <p>Gansu Assessment Center of Mineral Resources ReservesLanzhou China;</p> <p>Geological Survey of Gansu ProvinceLanzhou China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/165.html" title="地质学">地质学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gold occurrence&option=203" rel="nofollow">gold occurrence;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pb isotope&option=203" rel="nofollow">Pb isotope;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pyrite&option=203" rel="nofollow">pyrite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=West Qinling orogenic belt&option=203" rel="nofollow">West Qinling orogenic belt;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zaozigou gold deposit&option=203" rel="nofollow">Zaozigou gold deposit;</a> </p> <div class="translation"> 机译：黄金发生;Pb同位素;黄铁矿;西秦岭造山带;枣嘴沟金矿床; </div> </li> </ul> </div> </div> <div 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