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首页> 外文期刊>Russian Journal of General Chemistry >Some Features of Reaction of 2-Methyl-1,4-naphthoquinone with H-Phosphonium Salts Based on Diphenylphosphine
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Some Features of Reaction of 2-Methyl-1,4-naphthoquinone with H-Phosphonium Salts Based on Diphenylphosphine

机译:基于二苯基膦的H-鏻盐的2-甲基-1,4-萘醌反应的一些特征

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摘要

It was shown that the direction of the reaction of 2-methyl-1,4-naphthoquinone with H-phosphonium salts obtained from diphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acids depends on the nature of the anion. Structure of the obtained mono- and diphosphinates, as well as the quasi-phosphonium salt, was established by NMR spectroscopy and single crystal X-ray diffraction methods.
机译:结果表明,2-甲基-1,4-萘醌与由二苯基膦和三氟甲磺酸或三氟乙酸获得的H-鏻盐的反应的方向取决于阴离子的性质。 通过NMR光谱和单晶X射线衍射方法建立所得单磷酸盐和二磷酸的结构,以及准鏻盐。

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