Quantum-chemical models of the molecular structures of open-chain and macrocyclic d-metal chelates with (N,O)- and (N,S)-donor polydentate ligands

Mikhailov O. V.

首页> 外文期刊>Russian Journal of Inorganic Chemistry >Quantum-chemical models of the molecular structures of open-chain and macrocyclic d-metal chelates with (N,O)- and (N,S)-donor polydentate ligands

【24h】

Quantum-chemical models of the molecular structures of open-chain and macrocyclic d-metal chelates with (N,O)- and (N,S)-donor polydentate ligands

机译：用（N，O） - 和（n，s） - 络络配体的露头和大环D-金属螯合物分子结构的量子化学模型

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The results of quantum-chemical calculations of the molecular structures of d-metal chelate complexes with compartmental and macrocyclic ligands arising as a result of "self-assembly" processes (template synthesis) to form so-called open and closed contours around the complexing agent have been systematized and generalized. In general, for compounds of both the first and second groups, molecular structures with noncoplanar chelate cores and macrocyclic moieties are more characteristic than coplanar ones. The review covers the works of the author and other researchers carried out mainly over the past 20 years.

机译：随着“自组装”方法（模板合成）的结果，由分区和宏环配体与分区和宏环配体的分子结构的量子化学计算结果，以形成络合剂周围的所谓的开放和闭合轮廓已经系统化和广泛化。通常，对于第一和第二组的化合物，具有非平板螯合物芯和宏环部分的分子结构比共甘露糖更具有更特征。审查涵盖了提交人的作品，其他研究人员主要在过去20年中进行。

著录项

来源
《Russian Journal of Inorganic Chemistry》 |2017年第13期|共18页
作者
Mikhailov O. V.;
展开▼
作者单位

Kazan Natl Res Technol Univ Kazan 420015 Tatarstan Russia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Quantum-chemical models of the molecular structures of open-chain and macrocyclic d-metal chelates with (N,O)- and (N,S)-donor polydentate ligands [J] . Mikhailov O. V. Russian Journal of Inorganic Chemistry . 2017,第13期

机译：用（N，O） - 和（n，s） - 络络配体的露头和大环D-金属螯合物分子结构的量子化学模型
2. DFT Quantum-Chemical Calculations of Molecular Structures for Template Heteroligand (5757)Macrocyclic M(II) Chelates of 3d Elements with a 16-Membered Macrocyclic Ligand and Br- Ions [J] . Mikhailov O. V., Chachkov D. V. Russian Journal of Inorganic Chemistry . 2017,第9期

机译：DFT量子化学计算模板杂酚（5757）杂环（5757）的三维元素螯合物与16-元大环配体和BRIE
3. Quantum-Chemical Model for the Formation of the Coordination Mode Structure of Be(II), Ni(II), Pd(II), Pt(II), and Hg(II) Bis(chelate) Complexes with Polydentate Azomethine Ligands [J] . Kharabayev N. N., Starikov A. G., Minkin V. I. Russian Journal of Coordination Chemistry . 2015,第7期

机译：Be（II），Ni（II），Pd（II），Pt（II）和Hg（II）双（螯合物）与多齿甲亚胺配体配合物的配位模式结构形成的量子化学模型。
4. DFT Study of Adiabatic Singlet-Triplet Energy Gaps in Ni(II)-based Macrocyclic-ligand Supramolecular Complexes [C] . Alex-Adrian Farcas, Attila Bende International Conference of Processes in Isotopes and Molecules . 2020

机译：Ni（II）中绝热单态三重态能量间隙的DFT研究 - 基于大环 - 配体超分子复合物
5. Coordination chemistry of noncyclic and macrocyclic thioether-diazine polydentate ligands. [D] . Chen, Liqin. 1993

机译：非环状和大环硫醚-二嗪多齿配体的配位化学。
6. DFT Quantum-Chemical Modeling Molecular Structures of Cobalt Macrocyclic Complexes with Porphyrazine or Its Benzo-Derivatives and Two Oxygen Acido Ligands [O] . Oleg V. Mikhailov, Denis V. Chachkov 2020

机译：用卟啉或苯并衍生物和两种氧己烯配体的DFT量子化学模拟钴宏环复合物的分子结构
7. DFT Quantum-Chemical Modeling Molecular Structures of Cobalt Macrocyclic Complexes with Porphyrazine or Its Benzo-Derivatives and Two Oxygen Acido Ligands [O] . Oleg V. Mikhailov, Denis V. Chachkov 2020

机译：用卟啉或苯并衍生物和两种氧己烯配体的DFT量子化学模拟钴宏环复合物的分子结构
8. Tris (phenyl (difluorophosphino) amino)phosphine (P(N(C6H5)PF2)3), a Novel Tridentate Strong pi-Accept-or Ligand Forming Cage Chelates. Crystal Structure of the Chelate Complex P(N(C6H5)PF2)3Mo(CO)3 [R] . Brown, G. M., Finholt, J. E., King, R. B., 1981

机译：三（苯基（二氟膦基）氨基）膦（p（N（C6H5）pF2）3），新型三齿强π-接受 - 或配体形成笼螯合物。螯合物p（N（C6H5）pF2）3mo（CO）3的晶体结构

Quantum-chemical models of the molecular structures of open-chain and macrocyclic d-metal chelates with (N,O)- and (N,S)-donor polydentate ligands

摘要

著录项

相似文献

相关主题

期刊订阅