Effect of Microwave Radiation on the Solvent-Free Synthesis of MOF-199

Kudelin A. K.

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Effect of Microwave Radiation on the Solvent-Free Synthesis of MOF-199

机译：微波辐射对MOF-199无溶剂合成的影响

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MOF-199 was synthesized in two ways: mechanochemical and microwave activation. The synthesized materials were characterized by X-ray diffraction and the Klyachko-Gurvich technique of measuring their specific surface areas. Rotational spectra were modeled for compounds representing the most important ligands in the synthesis of MOF-199-like structures: 1,3,5-benzenetricarboxylic acid, 2-methylimidazole, terephthalic acid, and 2,5-dihydroxyterephthalic acid. Based on the resulting data, an explanation was proposed for the abnormal behavior of the 1,3,5-benzenetricarbolxylic acid-copper(II) acetate reaction mixture under conditions of microwave activation and the impossibility of synthesizing MOFs from terephthalic and 2,5-dihydroxyterephthalic acids without a solvent.

机译：MOF-199以两种方式合成：机械化学和微波活化。通过X射线衍射和测量其特定表面积的klyachko-gurvich技术以合成材料为特征。用于模拟旋转光谱，用于代表合成MOF-199样结构中最重要的配体的化合物：1,3,5-苯甲酸，2-甲基咪唑，对苯二甲酸和2,5-二羟基苯二甲酸。基于所得到的数据，提出了在微波活化条件下为1,3,5-苯甲酰基甲酸 - 铜（II）乙酸盐反应混合物的异常行为的说明，并且不可能从对苯二甲酸合成MOF和2,5- 二羟基苯二甲酸没有溶剂。

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来源
《Russian Journal of Physical Chemistry》 |2018年第12期|共3页
作者
Kudelin A. K.;
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作者单位

Moscow MV Lomonosov State Univ Dept Chem Moscow 119992 Russia;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
MOF-199; metal organic framework; solvent-free synthesis; microwave synthesis;

机译：MOF-199;金属有机框架;无溶剂合成;微波合成;

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Effect of Microwave Radiation on the Solvent-Free Synthesis of MOF-199

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