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Effect of stretch ratio on the induced crystallinity and mechanical properties of biaxially stretched PET

机译:拉伸比对双轴拉伸宠物诱导结晶度和力学性能的影响

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摘要

Semi-crystalline polymers are observed to change their mechanical properties upon processing due to the changes in the crystallinity of the polymer. This paper investigates the changes in the crystallinity and mechanical properties of biaxially stretched polyethylene terephthalate, PET, for different stretch ratios (or strains). Each stretched PET sample was heated to 100 degrees C in a biaxial stretching machine before being stretched to the desired stretch ratio. The same strain rate of 2/s was used for the stretching and mode of deformation was simultaneous on either side. Differential Scanning Calorimetry (DSC) was used to investigate the variation of induced crystallinity with stretch ratio. Tensile tests were used to determine the variation of the processing stretch ratios with mechanical properties. The results show that the higher the stretch ratio, the higher the amount of induced crystallinity in the PET sample. Also, the higher the stretch ratio, the better the mechanical properties.
机译:由于聚合物的结晶度的变化,观察到半结晶聚合物在加工时改变其机械性能。本文研究了不同拉伸比(或菌株)双轴拉伸聚对苯二甲酸乙二醇酯的结晶度和力学性能的变化。在拉伸到所需的拉伸比之前,将每个拉伸的PET样品加热至100摄氏度。使用相同的2 / s应变速率用于拉伸和变形模式在任一侧上同时进行。使用差扫描量热法(DSC)来研究诱导结晶度的变化与拉伸比。使用拉伸试验来确定具有机械性能的加工拉伸比的变化。结果表明,拉伸比越高,PET样品中诱导结晶度越高。而且,拉伸比越高,机械性能越好。

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