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首页> 外文期刊>Physica Scripta: An International Journal for Experimental and Theoretical Physics >Growth and study of nonlinear optical P-dimethyl-aminobenzaldehyde crystal for photonic device application
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Growth and study of nonlinear optical P-dimethyl-aminobenzaldehyde crystal for photonic device application

机译:用于光子器件应用的非线性光学对二甲基 - 氨基甲醛晶体的生长和研究

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摘要

Pera dimethyl-aminobenzaldehyde (p-DMAB) is a well known aromatic compound with nonlinear optical properties in various application fields such as optoelectronics, photonics etc. The single crystal of p-DMAB is grown by slow evaporation technique (constant temperature bath) at room temperature. These grown crystals are good in size with transparent appearance. The grown crystals are characterized using x-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, elemental analysis, UV-spectroscopy, second harmonic generation (SHG), optical limiter behavior, Vickers hardness, scanning electron microscopy (SEM). Single crystal XRD provides information about the crystal structure. The powder XRD shows that material is crystalline in nature. FTIR-spectroscopy provides information about the relevant functional group present in the compound. Carbon-hydrogen-nitrogen analysis shows appropriate composition of these elements within this material. UV-vis study reveals that materials have wide window over the entire visible region. The observed order of refractive index points their use in anti-refracting coating devices. Good linear polarisability, susceptibility, optical conductivity data are also appropriate to decide their use in optical device fabrications. Wider optical band gap described dielectric behavior of material. SHG test shows that material has 2.03 times greater efficiency than the reference material KDP. Moreover the emission of green light indicates that the material can be used to develop green-blue laser. Optical limiter behavior shows that material is suitable for fabrication of an optical limiter device. The Vicker's microhardness study was also carried out on the sample. Vickers hardness test shows increment in hardness, yield strength and stiffness of material. SEM images show smooth morphology at different magnifications.
机译:PERA二甲基 - 氨基苯并醛(P-DMAB)是众所周知的芳族化合物,其各种施用领域中具有非线性光学性质,例如光电子,光子件等。通过缓慢蒸发技术(恒温浴)在室内生长P-DMAB的单晶温度。这些生长的晶体的尺寸良好,外观透明。生长的晶体的特征在于使用X射线衍射(XRD),傅里叶变换红外(FTIR)光谱,元素分析,UV光谱,二次谐波产生(SHG),光学限制器行为,维氏硬度,扫描电子显微镜(SEM)。单晶XRD提供有关晶体结构的信息。粉末XRD显示材料本质上是结晶。 FTIR-光谱学提供有关化合物中存在的相关功能组的信息。碳 - 氢 - 氮分析显示该材料内这些元素的适当组成。 UV-VIS研究表明,材料在整个可见区域上有宽窗口。观察到的折射率顺序点将其用于防折射涂层装置。良好的线性可聚焦性,敏感性,光学电导率数据也适合于决定它们在光学器件结构中的使用。更宽的光带隙描述了材料的介电行为。 SHG测试表明,效率高于参考材料KDP的材料具有2.03倍。此外,绿光的发射表明材料可用于开发绿色蓝色激光器。光学限制器行为表明,材料适用于制造光学限制器装置。在样品上也进行了维氏微硬度研究。维克斯硬度试验显示硬度,屈服强度和材料刚度的增量。 SEM图像显示不同放大倍数的平滑形态。

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