Surface modification of reduced graphene oxide‐polyaniline nanotubes nanocomposites for improved supercapacitor electrodes

摘要

Abstract > In the present work, irradiation with high energetic ions has been used for surface, structural, and morphological modifications of reduced graphene oxide (RGO) and polyaniline nanotubes (PAniNTs) nanocomposites with a view to enhance their electrochemical performance as supercapacitor electrode. High‐resolution transmission electron microscope micrographs depict defect induced fragmented morphology with stable inner hollow tubes up to a fluence of 2.2?×?10 12 ions cm ?2 , above which drastic degradation of PAniNTs is observed. Irradiation induced annealing effects and structural disorder at varied irradiation fluences have been investigated by micro‐Raman spectroscopy. Formation of shorter PAniNTs of higher surface area due to generation of ion irradiation induced defects and their reorganization results in increased Brunauer‐Emmett‐Teller specific surface area and porosity. Surface energy and wettability of the electrodes increase upon ion irradiation, which improves electrode‐electrolyte interaction at the interface. Surface free energy calculations indicate increased concentration of polar groups on the nanocomposite electrode surface upon irradiation. Electrochemical performance studies indicate enhancement in specific capacitance and cyclic stability from 448 F g ?1 and 89% for unirradiated nanocomposite to 482 F g ?1 and 92%, <sub>,</sub> respectively, for the nanocomposite irradiated at 2.2?×?10 12 ions cm ?2 fluence, which is attributed to the increased surface energy and porosity upon irradiation giving rise to increased electrochemically active sites for charge storage in the electrode. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在本作的工作中，具有高能离子的照射已经用于表面，结构和形态学修饰，所述石墨烯（RGO）和聚苯胺纳米管（球孔纳米管（面板）纳米复合材料的表面，结构和形态学修饰，以提高其作为超级电容器电极的电化学性能。高分辨率透射电子显微镜显微照片描绘缺陷诱导碎片形态与稳定的内部空心管，高于2.2？×10 12 </ sup> 离子厘米？2 </ sup> 以上观察到剧本的急性降解。通过微拉曼光谱研究了辐照诱导的退火效应和各种辐射流量的结构障碍。由于离子照射诱导缺陷的产生，形成更短的表面积的形成和它们的重组导致Brunauer-Emmett-Treater特定表面积和孔隙率增加。电极的表面能和润湿性在离子照射时增加，这改善了界面处的电极电解质相互作用。表面自由能量计算表示照射时纳米复合电极表面上的极性基团的浓度增加。电化学性能研究表明448 f g的特定电容和循环稳定性的增强？1 </ sup> 未照射的纳米复合材料为89％至482 f g ？1 </ sup> 和92％， <sub>，</ sub> 分别用于在2.2℃照射的纳米复合材料？×10 12 </ sup> 离子厘米？2 </ sup> 注重归因于在照射时的表面能和孔隙率增加，从而产生电极储存的电化学活性位点。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29566/'>《Polymer Composites》</a> <b style="margin: 0 2px;">|</b><span>2020年第2期</span><b style="margin: 0 2px;">|</b><span>共15页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7852.html" title="增强塑料、填充塑料">增强塑料、填充塑料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conducting polymers&option=203" rel="nofollow">conducting polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=irradiation&option=203" rel="nofollow">irradiation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=modification&option=203" rel="nofollow">modification;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanocomposites&option=203" rel="nofollow">nanocomposites;</a> </p> <div class="translation"> 机译：导电聚合物;电化学;辐照;修饰;纳米复合材料; 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CAI Xiao-sheng</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡晓生&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,蔡晓生</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ZHANG Qi-lu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,ZHANG Qi-lu</a> <span> <a href="/conference-cn-6449/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国核学会2013年学术年会 </a> <span> <span> . 2013</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316037995.html">基于石墨烯/W18O49纳米复合材料与聚苯胺组合的电致变色超级电容器研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李雨婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李雨婷</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120100661145.html">超级电容器用石墨烯聚苯胺层状纳米复合材料的制备方法</a> <b>[P]</b> . <span> 中国专利： CN109659165A </span> <span> . 2019-04-19</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061203014004.html">一种氢氧化镍/石墨烯纳米复合材料及其制备方法、超级电容器电极及超级电容器</a> <b>[P]</b> . <span> 中国专利： CN106158405B </span> <span> . 2018.08.31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130408741238.html">REDUCED GRAPHENE OXIDE/CARBON NANOTUBE/MANGANESE DIOXIDE COMPLEX FOR HIGH-PERFORMANCE SUPERCAPACITOR ELECTRODE MATERIALS, AND PREPARATION METHOD THEREOF</a> <b>[P]</b> . <span> 外国专利：  KR20170026842A </span> <span> . 2017-03-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于高性能超级电容器电极材料的还原氧化石墨烯/碳纳米管/氧化锰复合物及其制备方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130408562855.html">// Reduced graphene oxide/carbon nanotube/manganese dioxide composite for supercapacitor electrode materials and preparation method thereof</a> <b>[P]</b> . <span> 外国专利：  KR101772755B1 </span> <span> . 2017-08-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：//用于超级电容器电极材料的还原氧化石墨烯/碳纳米管/二氧化锰复合材料及其制备方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130500004702.html">REDUCED GRAPHENE OXIDE/MANGANESE(IV) OXIDE NANOCOMPOSITE AND ELECTRODE COMPRISING SAME, METHOD OF MANUFACTURE OF VARIOUS GRAPHENE MATERIAL/METAL OXIDE NANOCOMPOSITES</a> <b>[P]</b> . <span> 外国专利：  US2021159490A1 </span> <span> . 2021-05-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> 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