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Nitrato Functionalized Polymers for High Energy Propellants and Explosives: Recent Advances

机译：高能量推进剂和爆炸物的亚硝酸盐官能化聚合物：最近的进展

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摘要

Future propellants and explosive research focus on developing compositions with less vulnerability without compromising performance. This has provided impetus for research in the area of high energy materials and compounds free from pollution, for safe handling, high performance, reliability and reproducibility. The energetic oxidizers and energetic binders are being developed in this scenario for use in composite propellants and explosives. In a propellant, the binder holds together the matrix containing solid oxidizer particles and finely divided metal particles. It provides structural integrity and aid the combustion of the propellant. Any new development in this area wherein the binder can contribute to the energetic is of immense importance. This can be achieved by incorporation of energetic groups such as nitrato (-ONO2), azide (-N-3) or flurodinitro CF(NO2)(2) as side chain or on to the existing polymer backbone. Among these, nitrato functionalized energetic binders can find application in myriad areas like boosters, plastic bonded explosives, gas generators and pyrogen igniters. The present article is a concise review on various types of nitrato binders; their synthesis, properties and their propellant studies. Copyright (c) 2017 John Wiley & Sons, Ltd.
机译：未来推进剂和爆炸性研究重点是在不影响性能的情况下开发具有较少脆弱性的组合物。这为高能量材料和无污染的化合物的研究提供了推动，可用于安全处理，高性能，可靠性和再现性。在这种情况下，在这种情况下开发了能量氧化剂和能量粘合剂，用于复合推进剂和炸药。在推进剂中，粘合剂将含有固体氧化剂颗粒的基质和细碎的金属颗粒固定在一起。它提供了结构完整性并辅助推进剂的燃烧。该领域的任何新的开发，其中粘合剂可以促进精力充沛的重要性。这可以通过将诸如硝基（-NO 2），叠氮化物（-N-3）或氟癸钛腈CF（NO 2）（2）作为侧链或对现有的聚合物主链的能量组来实现。其中，硝基官能化的能量粘合剂可以在Myriad领域找到应用，如助推器，塑料粘合炸药，气体发生器和热原子点燃。本文对各种类型的硝酸氮粘合剂进行了简明的综述;它们的合成，性质及其推进剂研究。版权所有（c）2017 John Wiley＆Sons，Ltd。

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