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首页> 外文期刊>Corrosion Engineering, Science and Technology >Some scientific considerations on the article: 'Scientific basis for corrosion of copper in water and implications for canister lifetimes' published by F. King and C. Lilja
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Some scientific considerations on the article: 'Scientific basis for corrosion of copper in water and implications for canister lifetimes' published by F. King and C. Lilja

机译:F. King和C.Lilja发表的文章“在水中腐蚀铜的科学依据及其对罐寿命的影响”上有一些科学考虑。

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摘要

There has for the past 30 years been a debate regarding whether corrosion of copper can occur in anoxic water. In short the debate has been between experiments showing that corrosion of copper can occur and theory that predicts that it will not occur. The thermodynamics of copper corrosion, particularly, that copper cannot corrode in anoxic water, is a fundamental prerequisite for the Swedish repository concept for spent nuclear fuel developed by the Swedish Nuclear Fuel and Waste Management Company (SKB). Thus, in 1986 and subsequently Hultquist and coworkers experimentally confirmed that corrosion of copper can occur in some conditions. However, this research is generally assumed to be incorrect, most recently by a paper by King and Lilja in this journal. In this article I will develop the argument that Hultquist's work should not be so disregarded.
机译:在过去的30年中,关于缺氧水中是否会发生铜腐蚀一直存在争议。简而言之,争论是在表明可能发生铜腐蚀的实验与预测不会发生铜腐蚀的理论之间进行的。铜腐蚀的热力学,尤其是铜不能在缺氧水中腐蚀的热力学,是瑞典核燃料和废物管理公司(SKB)开发的瑞典乏核燃料储存概念的基本前提。因此,在1986年以及随后的Hultquist及其同事实验确定,在某些条件下会发生铜腐蚀。但是,一般认为这项研究是不正确的,最近,King和Lilja在该期刊上发表了一篇论文。在本文中,我将提出一个论点,即不应如此忽视Hultquist的工作。

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