Stability of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-Diolate (TKX-50) in Solvents

Jia Jianhui; Xu Jinjiang; Cao Xiong; Li Shichun; Huang Shiliang; Liu Yu; Li Jinshan

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Stability of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-Diolate (TKX-50) in Solvents

机译：二羟基铵5,5'-双级四唑-1,1'-二氢醇（TKX-50）的稳定性溶剂

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The stability of solid TKX-50 has attracted considerable attention. However, the stability of TKX-50 in solvents has not been investigated sufficiently yet. Herein, the stability of TKX-50 in various solvents, including N, N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), acetone, deionized water, ethyl acetate, acetonitrile, methanol, ethanol, petroleum ether, hexane, DMF/acetone (mixture of DMF and acetone) and DMF/DMSO (mixture of DMF and DMSO), has been studied. The results show that TKX-50 remains stable in DMSO, deionized water, ethyl acetate, acetonitrile, methanol, ethanol, petroleum ether and hexane. It is remarkable that TKX-50 can react with DMF in different ways under different conditions, such as a wide temperature range from 25 degrees C to 150 degrees C. The products in reactions between TKX-50 and DMF were dimethylammonium 5, 5'-bistetrazole-1-hydroxy-1'-oxygen (DMA-BTO), dimethylamine 5, 5'-bistetrazole-1, 1'-diolate (2DMA-BTO) and diammonium 5,5'-bistetrazole-1,1'-diolate (ABTOX), which were confirmed by single crystal diffraction, respectively. Moreover, the thermal stability of the products and the interconversion pathways between TKX-50 and products were determined. Subsequently, the reaction mechanism of TKX-50 in DMF solvent has been inferred.

机译：固体TKX-50的稳定性引起了相当大的关注。然而，溶剂中TKX-50的稳定性尚未充分研究。在此，在各种溶剂中TkX-50的稳定性，包括N，N-二甲基甲酰胺（DMF），二甲基亚砜（DMSO），丙酮，去离子水，乙酸乙酯，乙腈，甲醇，乙醇，石油醚，己烷，DMF /丙酮（DMF和丙酮的混合物）和DMF / DMSO（DMF和DMSO的混合物）已经研究过。结果表明，TKX-50在DMSO，去离子水，乙酸乙酯，乙腈，甲醇，乙醇，石油醚和己烷中保持稳定。显着的是，TKX-50可以在不同的条件下以不同的方式与DMF反应，例如从25摄氏度至150℃的宽温度范围。TKX-50和DMF之间的反应中的产物是二甲基铵5，5' Bistetrazole-1-羟基-1'-氧（DMA-BTO），二甲胺5,5'-双级四唑-1,1'二甲磺酸盐（2DMA-BTO）和二醇5,5'-双级四唑-1,1'-二氢盐（ABTOX）分别通过单晶衍射证实。此外，确定了产物的热稳定性和TKX-50和产物之间的互连途径。随后，已经推断了DMF溶剂中TKX-50的反应机理。

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来源
《Propellants, Explosives, Pyrotechnics》 |2019年第8期|共11页
作者
Jia Jianhui; Xu Jinjiang; Cao Xiong; Li Shichun; Huang Shiliang; Liu Yu; Li Jinshan;
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CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

North Univ China Taiyuan 030051 Shanxi Peoples R China;

CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

CAEP Inst Chem Mat Mianyang 621900 Sichuan Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类爆炸物工业、火柴工业;
关键词
solvent; stability; TKX-50;

机译：溶剂;稳定性;TKX-50;

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1. Stability of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-Diolate (TKX-50) in Solvents [J] . Jia Jianhui, Xu Jinjiang, Cao Xiong, Propellants, Explosives, Pyrotechnics . 2019,第8期

机译：二羟基铵5,5'-双级四唑-1,1'-二氢醇（TKX-50）的稳定性溶剂
2. Two-sided effects of strong hydrogen bonding on the stability of dihydroxylammonium 5,5 '-bistetrazole-1,1 '-diolate (TKX-50) [J] . Meng Liya, Lu Zhipeng, Wei Xianfeng, CrystEngComm . 2016,第13期

机译：强氢键对5,5'-双四唑-1,1'-二醇酯（TKX-50）的二羟基铵稳定性的双面影响
3. Two-dimensional nanoscale MoS2 for thermal catalysis of dihydroxylammonium-5,5 '-bistetrazole-1,1 '-diolate (TKX-50) [J] . Li Xiaoxia, Cao Xiong, Bai Xueyuan, Journal of thermal analysis and calorimetry . 2021,第4期

机译：二维纳米级MOS2用于热催化二羟基铵-5,5'-bistetrazole-1,1' - 二醇（TKX-50）
4. Thermal hazard analysis of dihydroxylammonium 5,5?-bistetrazole-1,1?-diolate (TKX-50) [C] . Hu Niu, Shusen Chen, Shaohua Jin, North American Thermal Analysis Society conference . 2018

机译：5,5′-双四唑-1,1′-二醇二羟基铵（TKX-50）的热危害分析
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机译：（I）〜WF（6），ReF（6），OsF（6），IrF（6），PtF（6），O（2）+ PtF（6）-的气相电子衍射研究; （II）〜3-氨基丙烯醛; （III）〜3-氯-1-丙醇; （IV）〜2,2'，5,5'-四甲基-1,1'-二茂铁。
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Stability of Dihydroxylammonium 5,5'-Bistetrazole-1,1'-Diolate (TKX-50) in Solvents

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