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Thermal degradation of alloy CCA617 in pure steam at 750 and 850 degrees C

机译:750和850摄氏度的纯蒸汽中CCA617合金的热降解

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Oxidation and oxidation-induced microstructure evolution of CCA617 alloy was studied in pure steam at 750 and 850 degrees C. Results showed that the alloy was oxidised approximately following a parabolic law. Temperature increase greatly promoted the external and internal oxidation. A single (Cr, Mn)(2)O-3 layer with distribution of minor TiO2 and MnCr2O4 formed at 750 degrees C whereas a duplex oxide scale formed at 850 degrees C consisting of a thin MnTiO3 outer layer and a thicker (Cr, Mn)(2)O-3 inner layer. TiO2 and Al2O3 were formed internally especially along grain boundaries. Intragranular Mo-rich M23C6 type carbides were also observed. The carbides dissolved into the matrix as oxidation progressed. Based on detailed compositional and microstructural characterisation of the oxidised alloy, the mechanisms of external and internal oxidation as well as dissolution of the intragranular carbides are presented.
机译:在750和850摄氏度的纯蒸汽中研究了CCA617合金的氧化和氧化诱导的组织演变。结果表明,该合金大约遵循抛物线定律被氧化。温度的升高大大促进了内部和外部的氧化。在750摄氏度时形成具有少量TiO2和MnCr2O4分布的单一(Cr,Mn)(2)O-3层,而在850摄氏度时形成的双相氧化皮由薄的MnTiO3外层和较厚的(Cr,Mn )(2)O-3内层。 TiO2和Al2O3尤其是沿晶界内部形成。还观察到了晶内富Mo的M23C6型碳化物。随着氧化的进行,碳化物溶解到基体中。基于氧化合金的详细组成和微观结构特征,提出了内部和内部氧化以及粒内碳化物溶解的机理。

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