General trends in concentration and temperature behavior of equivalent conductance of <Emphasis Type='Italic'>N,N</Emphasis>-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure

L. M. Timofeeva; I. V. Balakaeva; A. S. Lileev; Yu. A. Simonova; A. K. Lyashchenko

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General trends in concentration and temperature behavior of equivalent conductance of N,N-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure

机译：<重点型=“斜体”> N，N -dalylammonium聚合物水溶液的浓度和温度行为的浓度和温度行为的一般趋势：抗衡离子性质和胺结构的影响

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AbstractThe specific and equivalent conductivity of the diluted aqueous solutions of diallyammonium polyelectrolytes, initial monomers (N,N-diallylammonium trifluoroacetate,N,N-diallyl-N-methylammonium trifluoroacetate,N,N-diallyl-N,N-dimethylammonium chloride), and also potassium trifluoroacetate and trifluoroacetic acid solutions are studied. The limiting ionic mobility of diallylammonium cations and trifluoroacetate anion are found. The regularities of concentration changes in the equivalent conductance of polyelectolytes solutions are established. The degree of dissociation of diallyammonium polymers is shown to depend both on the counterion nature and on the amine structure.]]>

机译：<！[CDATA [<标题>抽象 ara>稀释的稀释水溶液的稀释水溶液的特定和等效电导率，初始单体（<重点型=“斜体”> n ，<重点类型=“斜体”> n - 三氟丙酸钙，<重点型=“斜体”> n ，<重点类型=“斜体”> n -dialel- <重点类型=“斜体“> N - 甲基三氟乙酸甲基甲基丙基铵，<重点型=”斜体“> n ，<重点型=”斜体“> n -dialel- <重点类型=”斜体“> n ，<强调型=“斜体”> N -D甲基氯化铵），并且研究了三氟乙酸钾和三氟乙酸溶液。发现了二烯醇铵阳离子和三氟乙酸盐阴离子的限制离子迁移率。建立了聚溶解溶液等同电解溶液等同电压的浓度变化的规律。显示二烷铵聚合物的解离程度依赖于抗衡性和胺结构。]>

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《Polymer science, Series C》 |2017年第1期|共8页
作者
L. M. Timofeeva; I. V. Balakaeva; A. S. Lileev; Yu. A. Simonova; A. K. Lyashchenko;
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Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences;

Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

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机译：<重点型=“斜体”> N，N -dalylammonium聚合物水溶液的浓度和温度行为的浓度和温度行为的一般趋势：抗衡离子性质和胺结构的影响
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机译：胶体溶液的介电研究。 II。小抗衡离子在同源长链胺的盐酸盐水溶液中的行为

General trends in concentration and temperature behavior of equivalent conductance of N,N-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure

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