Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum.

Asai R; Shigetomi K; Ubukata M

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Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum.

机译：（ - ） - 林磺酚A和（ - ） - 血红蛋白C的绝对配置，由GloeoSteReum Incarnatum产生的。

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Gloeostereum incarnatum is an edible mushroom that appears on broad-leaved wood in eastern Asia, northern Japan, northern China and eastern Siberia.1'2 We have focused our attention on library construction of fungal strains of mushrooms as a screening source for the biologically active small molecules useful for forward chemical genetics and development of medicinal remedy. During the course of the screening program for potential chemopreventive agents against murine B16 melanoma cells, we found potent antiproliferative activity in a culture broth of Gloeostereum incarnatum HUWCB-0029 picked in the Sapporo campus of Hokkaido University, Japan. The active compound, (—)-hirsutanol A (1), was purified with an inactive related compound, (—)-hirsutanol C (2), through bioassay-guided isolation. After derivatizing 1 to (+)-incarnal (3), we confirmed that the strain produced trace amount of 3 too.

机译：Gloeostereum Incarnatum是一个可食用的蘑菇，在东亚，日本北部，中国北部和西伯利亚北部和西伯利亚的阔叶木材中出现。小分子适用于前向化学遗传学和发育药物补救措施。在潜在化学预防剂对鼠B16黑色素瘤细胞的筛选方案过程中，我们发现了日本北海道大学札幌校区的GloeosteReum incarnatum Huwcb-0029的培养肉汤中有效的抗增殖活性。用生物测定引导的分离用无活性相关化合物，（ - ） - 林丁醇C（2）用无活性相关化合物纯化活性化合物（ - ） - 氯脲醇A（1）。在衍生1至（+） - 感知（3）后，我们证实该应变也产生了痕量的3。

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《The Journal of Antibiotics: An International Journal》 |2011年第10期|共4页
作者
Asai R; Shigetomi K; Ubukata M;
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Division of Applied Bioscience Graduate School of Agriculture Hokkaido University Sapporo Japan.;

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正文语种 eng
中图分类药学;
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1. Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum. [J] . Asai R, Shigetomi K, Ubukata M The Journal of Antibiotics: An International Journal . 2011,第10期

机译：牛油杆菌产生的（-）-hirsutanol A和（-）-hirsutanol C的绝对构型。
2. Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum. [J] . Asai R, Shigetomi K, Ubukata M The Journal of Antibiotics: An International Journal . 2011,第10期

机译：（ - ） - 林磺酚A和（ - ） - 血红蛋白C的绝对配置，由GloeoSteReum Incarnatum产生的。
3. Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum. [J] . Asai R, Shigetomi K, Ubukata M The Journal of Antibiotics: An International Journal . 2011,第10期

机译：（ - ） - 林磺酚A和（ - ） - 血红蛋白C的绝对配置，由GloeoSteReum Incarnatum产生的。
4. Comprehensive Determination of the Absolute Configurations of a Series of Novel Bitter Compounds Derived from Hop (Humulus lupulus L.) by the Crystalline Sponge Method [C] . Yoshimasa Taniguchi, Takashi Kikuchi, Makoto Fujita 日本化学会春季年会講演予稿集 . 2018

机译：通过晶体海绵法综合测定源自跳跃（Humulus Lupulus L.）的一系列新苦化合物的绝对配置
5. Determination of the Absolute Configuration of β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method Heteroatom-directed Acylation of Secondary Alcohols to Assign Absolute Configuration Total Synthesis of Illisimonin a Osmate Es [D] . Burns, Alexander Sunshine. 2020

机译：使用竞争对映选择性转化法测定β-chiral初级醇的绝对构型次原子为仲醇的酰化酰化，分配绝对构型Illisimonin的总合成渗透
6. Isolation and determination of absolute configurations of insect-produced methyl-branched hydrocarbons [O] . Jan E. Bello, J. Steven McElfresh, Jocelyn G. Millar 2015

机译：昆虫生产的甲基支链烃的绝对构型的分离和测定
7. Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum [O] . Asai, Ryo, Mitsuhashi, Shinya, Shigetomi, Kengo, 2011

机译：牛油杆菌产生的（-）-hirsutanol A和（-）-hirsutanol C的绝对构型
8. Dynamic Evaluation of Absolute Altimeter Configurations. [R] . johnson,neil a. debellis,william 1975

机译：绝对高度计配置的动态评估。

Absolute configurations of (-)-hirsutanol A and (-)-hirsutanol C produced by Gloeostereum incarnatum.

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