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Adsorption of Atmospheric Carbonate and Evolution of Acidity during Grinding of Abnormal Montmorillonite1

机译:异常麦芽酮磨削过程中大气碳酸盐和酸度演化的吸附

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摘要

Montmorillonite (MMt) from Tunisia has been subjected to fine grinding and studied using FTIR spectroscopy, X-ray diffractograms, BET surface area, Bronsted and Lewis acidity analyse, and FTIR spectroscopy. As a result, significant changes in structural vibrations when MMt was mechanochemically treated were revealed. These changes include: a shift and a gradual decrease of structural OH, Si-O, and M-OH groups (M: octahedral cations; Al, Mg and Fe), which means that an imperfection was formed in the crystal mineral via a mechanochemical treatment. The grinding is associated with amelioration of the oxidative power of clay, which is manifested by the sharpening of the infrared absorption shoulder near 880 cm-1. The thermo-FTIR adsorption of N-butylamine showed that acidity did not improve upon grinding. On the contrary, the mechanochemical treatment led to the creation of the basic sites which promote the adsorption of atmospheric dioxide carbon.
机译:来自突尼斯的Montmorillonite(MMT)已经进行了精细研磨,并使用FTIR光谱,X射线衍射图,BET表面积,伪装和路易斯酸度分析和FTIR光谱学研究。 结果,显示了MMT机械化学处理的结构振动的显着变化。 这些变化包括:换档和结构OH,Si-O和M-OH基团的逐渐减少(M:八面体阳离子; Al,Mg和Fe),这意味着通过机械化学材料在晶体矿物中形成缺陷 治疗。 研磨与粘土的氧化能力的改善有关,其通过锐化的红外吸收肩部靠近880cm-1而表现。 正丁胺的热纤维吸附显示酸度在研磨时不改善。 相反,机械化学处理导致促进大气二氧化碳吸附的基本位点。

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