Cobalt(II) and cobalt(III) coordination polymers constructed from flexible bis-imidazole and polycarboxyl co-ligands: syntheses, crystal structures and properties

Lu Jiu-Fu; Yu Xiao-Hu; Zhou Ke; Roy Soumendra Kumar; Yue Si-Yu; Li Li; Zhao Cai-Bin; Jin Ling-Xia

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Cobalt(II) and cobalt(III) coordination polymers constructed from flexible bis-imidazole and polycarboxyl co-ligands: syntheses, crystal structures and properties

机译：由柔性双咪唑和聚羧基共配体构成的钴（II）和钴（III）配位聚合物：合成，晶体结构和性能

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Two metal coordination polymers, namely {[Co(1,3-BIP)(OBA)]center dot 0.5H(2)O}(n) (SNUT-1) and [Co-2(mu-eta(1):eta(1)-O-2) (1,3-BIP)(2)(PMA)](n) (SNUT-2), where 1,3-BIP = 1,3-bis(imidazol) propane, H(2)OBA = 4,4'-oxybis(benzoate) and H(4)PMA = benzene-1,2,4,5-tetracarboxylic acid, were prepared by hydrothermal methods. Single-crystal X-ray analysis revealed that the structure of SNUT-1 consists of a 3D -> 3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (6(5).8) topology. The structure of SNUT-2 consists of a 3D framework which can be described as a (4,5)-connected binodal net with (4(2).6(3).8(4).10) (3(3).4(2).5) topology. The gas adsorption properties of SNUT-1 and photocatalytic activity of SNUT-2 for the degradation of Rhodamine B have been explored.

机译：两个金属配位聚合物，即{[CO（1,3-BIP）（OBA）]中心点0.5H（2）O}（N）（N）（SNUT-1）和[CO-2（MU-2（1）： η（1）-O-2）（1,3-BIP）（2）（PMA）]（N）（SNUT-2），其中1,3-BIP = 1,3-双（Imidazol）丙烷H. （2）OBA = 4,4,4'-oxybis（苯甲酸盐）和H（4）PMA =苯-1,2,4,5-四羧酸，通过水热方法制备。单晶X射线分析显示，SNUT-1的结构由3D - > 3D双重互穿网络组成，可以描述为具有（6（5）.8）拓扑的4连接的超透视网络。 SNUT-2的结构由3D框架组成，3D框架可以被描述为（4,5）连接的二叉网络（4（2）.6（3）.8（4）.10）（3（3） .4（2）.5）拓扑。探讨了荷胺B降解的甜菜-1和光催化活性的气体吸附性能。

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《Transition Metal Chemistry》 |2019年第7期|共7页
作者
Lu Jiu-Fu; Yu Xiao-Hu; Zhou Ke; Roy Soumendra Kumar; Yue Si-Yu; Li Li; Zhao Cai-Bin; Jin Ling-Xia;
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Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

Shaanxi Univ Technol Coll Chem &

Environm Sci Shaanxi Prov Key Lab Catalyt Fdn &

Applicat Hanzhong 723001 Peoples R China;

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1. Cobalt(II) and cobalt(III) coordination polymers constructed from flexible bis-imidazole and polycarboxyl co-ligands: syntheses, crystal structures and properties [J] . Lu Jiu-Fu, Yu Xiao-Hu, Zhou Ke, Transition Metal Chemistry . 2019,第7期

机译：由柔性双咪唑和聚羧基共配体构成的钴（II）和钴（III）配位聚合物：合成，晶体结构和性能
2. Novel cobalt(II) coordination polymers constructed from 3,3′,4,4′-oxydiphthalic acid and N-donor ligands: Syntheses, crystal structures, and magnetic properties [J] . Chu Q., Su Z., Fan J., Crystal growth & design . 2011,第9期

机译：由3,3'，4,4'-氧二邻苯二甲酸和N-给体配体构成的新型钴（II）配位聚合物：合成，晶体结构和磁性
3. Syntheses, crystal structures, electrochemical and photocatalytic properties of two mixed-ligand cobalt(II) coordination polymers based on flexible bis(2-methylbenzimidazole) dicarboxylic acid ligands [J] . Li Jun Xuan, Hou Suo Xia, Hao Zeng Chuan, Transition Metal Chemistry . 2017,第7期

机译：基于柔性双（2-甲基双咪唑）二羧酸配体的两个混合配体钴（II）配位聚合物的合成，晶体结构，电化学和光催化性能
4. Anion-regulated Mixed-valency of Cobalt(II/III) Centers in Non-Coulombic Ionic Crystals [C] . Nobuto Yoshinari, Akari Hashimoto, Motohiro Nakano 日本化学会春季年会 . 2020

机译：非库仑离子晶体中钴（II / III）中心的阴离子混合级
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. Crystal structure of a novel one-dimensional zigzag chain-like cobalt(II) coordination polymer constructed from 44′-bipyridine and 2-hydroxybenzoate ligands [O] . Thawanrat Saelim, Kittipong Chainok, Filip Kielar, 2020

机译：一种新型一维之曲链链状钴（II）配位聚合物的晶体结构由44-硼烷和2-羟基苯甲酸盐配体构成
7. Synthesis, Crystal Structures, and Magnetic Properties of Three Cobalt(II) Coordination Polymers Constructed from 3,5-Pyridinedicarboxylic Acid or 3,4-Pyridinedicarboxylic Acid Ligands [O] . Xiaojing Zhou, Xiaolei Guo, Lili Liu, 2019

机译：三种钴（II）配位聚合物的合成，晶体结构和磁性特征由3,5-吡啶二羧酸或3,4-吡啶羧酸配体构成
8. Inorganic Coordination Polymers. Part XIX. Steric Effects of Hydrocarbon Side Groups on the Structure and Properties of Zinc(II),Cobalt(II),Manganese(II),Nickel(II) and Copper(II) Bis(Phosphinates). [R] . gillman, h. d. eichelberger, j. l. 1975

机译：无机配位聚合物。第十九部分。烃侧基的立体效应对锌（II），钴（II），锰（II），镍（II）和铜（II）双（次膦酸盐）的结构和性质的影响。

Cobalt(II) and cobalt(III) coordination polymers constructed from flexible bis-imidazole and polycarboxyl co-ligands: syntheses, crystal structures and properties

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