Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) 22 ](BF 44 ) 22

Dorn Matthias; Mack Katharina; Carrella Luca M.; Rentschler Eva; F?rster Christoph; Heinze Katja

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Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) ₂2 ](BF ₄4 ) ₂2

机译：镍（II）膨胀三吡啶络合物的结构和电子性质[Ni（DDPD）<亚> 2 2]（BF _{4 4）_{2 2}}

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> The synthesis, structure in the solid state, electrochemical, magnetic and optical properties of a new nickel(II) complex [Ni(ddpd) ₂ ] 2+ bearing the tridentate N , N ′‐dimethyl‐ N , N ′‐dipyridin‐2‐ylpyridine‐2,6‐diamine (ddpd) ligand are presented. The optical properties are discussed within the framework of ligand field theory.

机译： >合成，结构中的固态，电化学，磁性和光学性质的新镍（II）复合物[Ni（DDPD）_{2 ] ^{2 + / sup>轴承的三齿 n ， n '-dimethyl- n ， n ' - 提出了双吡啶-2-基吡啶-2,6-二胺（DDPD）配体。在配体场理论的框架内讨论了光学性质。}}

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2018年第14期|共7页
作者
Dorn Matthias; Mack Katharina; Carrella Luca M.; Rentschler Eva; F?rster Christoph; Heinze Katja;
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作者单位

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10–14 55128 Mainz Germany;

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正文语种 eng
中图分类化学;
关键词
Spin‐flip; Ligand field theory; N ligands; Tridentate ligands; Nickel;

机译：自旋翻转;配体场理论;n配体;三叉子;镍;

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1. Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) ₂2 ](BF ₄4 ) ₂2 [J] . Dorn Matthias, Mack Katharina, Carrella Luca M., Zeitschrift fur Anorganische und Allgemeine Chemie . 2018,第14期

机译：镍（II）膨胀三吡啶络合物的结构和电子性质[Ni（DDPD）<亚> 2 2]（BF _{4 4）_{2 2}}
2. Synthesis, magnetic properties, and electronic spectra of bis(beta-diketonato)chromium(III) and nickel(II) complexes with a chelated imino nitroxide radical: X-ray structures of [Cr(acaMe)(2)(IM2py)]PF6 and [Ni(acac)(2)(IM2py)] [J] . Tsukahara Y., Kamatani T., Iino A., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第17期

机译：具有螯合亚氨基亚硝基氮自由基的双（β-二酮基）铬（III）和镍（II）配合物的合成，磁性和电子光谱：[Cr（acaMe）（2）（IM2py）] PF6的X射线结构和[Ni（acac）（2）（IM2py）]
3. [Ni(L)(MeCN)][BF4](2) {L=2,5,8-trithia[9],(2,9)-1,10-phenanthro-linophane} as a building block for the synthesis of binuclear nickel(II) complexes: X-ray crystal structure and magnetochemistry of a singly F-bridged nickel(II) dimer [J] . Blake AJ., Devillanova FA., Garau A., Journal of the Chemical Society. Dalton Transactions . 2002,第23期

机译：[Ni（L）（MeCN）] [BF4]（2）{L = 2,5,8-trithia [9]，（2,9）-1,10-菲咯啉]作为合成的基础核镍（II）配合物：X射线晶体结构和单F桥式镍（II）二聚体的磁化学
4. Theoretical Studies on the Electronic Structures and Spectral Properties of Two Iridium(III) Complexes with Tetraphenylimidodiphosphinate Ligand [C] . Han De-ming, Zhang Gang, Zhao Li-hui International Conference onuture Optical Materials and Circuit Design . 2013

机译：用四苯基咪唑膦配体的两种铱（III）配合物的电子结构和光谱特性的理论研究
5. Syntheses, characterization and catalytic properties of Zn(II) and Ni(II) complexes: Modeling the active sites of zinc and nickel enzymes. [D] . Khan, Ahmad Raza. 1999

机译：Zn（II）和Ni（II）配合物的合成，表征和催化性能：模拟锌和镍酶的活性位点。
6. Crystal structure of a nickel compound comprising two nickel(II) complexes with different ligand environments: Ni(tren)(H2O)2Ni(H2O)6(SO4)2 [O] . Karilys González Nieves, Dalice M. Piñero Cruz 2020

机译：包含两个具有不同配体环境的镍（II）配合物的镍化合物的晶体结构：Ni（tren）（H2O）2 Ni（H2O）6（SO4）2
7. Ddpd as Expanded Terpyridine: Dramatic Effects of Symmetry and Electronic Properties in First Row Transition Metal Complexes [O] . Christoph Förster, Matthias Dorn, Thomas Reuter, 2018

机译：DDPD作为扩展的噻啶啉：对称性和电子特性在第一行过渡金属配合物中的戏剧效应

Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) 22 ](BF 44 ) 22

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Structure and Electronic Properties of an Expanded Terpyridine Complex of Nickel(II) [Ni(ddpd) ₂2 ](BF ₄4 ) ₂2