Coordination Polymers based on the Neutral Ditopic Ligand (C 66 H 44 PO(OCH 33 ) 22 ) 22 Involving some f‐Block Elements

Kreki? Kristijan; K?kel Eireen; Klintuch Dieter; Blo? Dana; Pietschnig Rudolf

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Coordination Polymers based on the Neutral Ditopic Ligand (C ₆6 H ₄4 PO(OCH ₃3 ) ₂2 ) ₂2 Involving some f‐Block Elements

机译：基于中性多型配体的配位聚合物（C _{6 6h _{4 4 po（och _{3 3）_{2 2）_{2 2涉及一些f块元素}}}}}

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> An improved synthesis using microwave heating affords (C ₆ H ₄ PO(OCH ₃ ) ₂ ) ₂ in excellent isolated yield (95?%). The ligand properties of this bisphosphonateester were explored towards hard metal centers M 2+ ( M = Ca, UO ₂ ) and M 3+ ( M = La, Ce, Sm, Eu) resulting in coordination polymers, for which the reduction of ionic size of the central metal atom resulted in lower‐dimensional structural motifs as opposed to higher dimensional networks obtained for the larger ions. All coordination polymers were characterized by single‐crystal X‐ray diffraction, IR spectroscopy, and combustion analysis. The ligand was furthermore characterized with multinuclear NMR spectroscopy.

机译： >使用微波加热提供改进的合成（C _{6 H _{4 Po（och _{3 ）<亚> 2 ）<亚> 2 优异的分离产率（95Ω％）。将该双膦酸盐的配体性能探索硬金属中心 m℃ 2 + / sop>（ m = ca，UO _{2 ）和 m 3 + （ m <= la，ce，sm，欧盟），导致配位聚合物，其中离子大小的降低中央金属原子导致下维结构基序，而不是为较大离子获得的高尺寸网络。通过单晶X射线衍射，红外光谱和燃烧分析表征所有配位聚合物。此外，配体的特征在于多核NMR光谱。}}}}

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2018年第3期|共6页
作者
Kreki? Kristijan; K?kel Eireen; Klintuch Dieter; Blo? Dana; Pietschnig Rudolf;
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作者单位

Institute of Chemistry and CINSaTUniversity of KasselHeinrich‐Plett‐Stra?e 40 34132 Kassel Germany;

Institute of Chemistry and CINSaTUniversity of KasselHeinrich‐Plett‐Stra?e 40 34132 Kassel Germany;

Institute of Chemistry and CINSaTUniversity of KasselHeinrich‐Plett‐Stra?e 40 34132 Kassel Germany;

Institute of Chemistry and CINSaTUniversity of KasselHeinrich‐Plett‐Stra?e 40 34132 Kassel Germany;

Institute of Chemistry and CINSaTUniversity of KasselHeinrich‐Plett‐Stra?e 40 34132 Kassel Germany;

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正文语种 eng
中图分类化学;
关键词
Phosphorus; Uranium; Lanthanides; Calcium; Coordination modes;

机译：磷;铀;镧系;钙;协调模式;

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1. Front Cover: Coordination Polymers based on the Neutral Ditopic Ligand (C ₆6 H ₄4 PO(OCH ₃3 ) ₂2 ) ₂2 Involving some f‐Block Elements (Z. Anorg. Allg. Chem. 3/2018) [J] . Kreki? Kristijan, K?kel Eireen, Klintuch Dieter, Zeitschrift fur Anorganische und Allgemeine Chemie . 2018,第3期

机译：前盖：基于中性DITopic配体的协调聚合物（C _{6 6 h _{4 4 po（och _{3 3）_{2 2）_{2 2涉及一些f块元素（z. anorg。allg。Chem。3/2018）}}}}}
2. Neutral mixed-metal coordination polymers based on a ditopic acetylacetonate, Mg(II) and Ag(I): syntheses, characterization and solvent-dependent topologies [J] . Guo Qianqian, Englert Ulli Dalton transactions: An international journal of inorganic chemistry . 2017,第26期

机译：基于DITopic乙酰丙酮，MG（II）和AG（I）的中性混合金属配位聚合物：合成，表征和溶剂依赖性拓扑
3. Spacer length-directed construction of two-dimensional [MoS_3Cu_3]-based coordination polymers from a precursor cluster [PPh_4][Cp*MoS_3(CuNCS)_3] (Cp* = η5-C_5Me_5) and 4-pyridyl-based ditopic ligands [J] . Wen-Hua Zhang, Hong Yu, Miao Yu, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：由前体簇[PPh_4] [Cp * MoS_3（CuNCS）_3]（Cp * =η5-C_5Me_5）和基于4-吡啶基的对位配体构成的基于二维基于[MoS_3Cu_3]的配位聚合物
4. Ion Exchange in Coordination Polymers Based on Phosphate Ligands [C] . Yuiko Tasaki-Handa 日本化学会春季年会講演予稿集 . 2018

机译：基于磷酸盐配体的配位聚合物中的离子交换
5. Coordination polymers and building blocks based on ditopic heteroscorpionate ligands. [D] . Santillan, Guillermo A. 2009

机译：基于对位异蝎子配体的配位聚合物和结构单元。
6. Coordination Polymers based on the Neutral Ditopic Ligand (C6H4PO(OCH3)2)2 Involving some f‐Block Elements [O] . Kristijan Krekić, Eireen Käkel, Dieter Klintuch, -1

机译：基于中性对位配体（C6H4PO（OCH3）2）2的配位聚合物涉及一些f-嵌段元素
7. New Antibacterial Silver(I) Coordination Polymers Based on a Flexible Ditopic Pyrazolyl-Type Ligand [O] . Aurel Tăbăcaru, Claudio Pettinari, Mariana Bușilă, 2019

机译：基于柔性DIToPIC吡唑基型配体的新型抗菌银（I）配位聚合物

Coordination Polymers based on the Neutral Ditopic Ligand (C 66 H 44 PO(OCH 33 ) 22 ) 22 Involving some f‐Block Elements

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Coordination Polymers based on the Neutral Ditopic Ligand (C ₆6 H ₄4 PO(OCH ₃3 ) ₂2 ) ₂2 Involving some f‐Block Elements